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- W4306408043 abstract "Glycerol (GLY) as a by-product in bio-diesel synthesis should be converted to more valuable compounds. In the present study, MgO/graphitic carbon nitride (MgO/g-C3N4) was synthesized and characterized using several techniques, including FESEM, Fourier transform infrared, X-ray diffraction, TEM, and CO2-TPD. The MgO/g-C3N4 catalysts illustrated high catalytic activity compared with pure g-C3N4 and MgO for conversion of glycerol to glycerol carbonate (GC) through transesterification reaction between GLY and dimethyl carbonate (DMC). According to the results, the optimum reaction conditions were: reaction time of 4 h, reaction temperature of 80°C, molar ratio of reactants (DMC:GLY) 3:1, and MgO/C3N4 catalyst dosage of 30 mg. The catalyst with a certain ratio of MgO:g-C3N4 = 6:1 showed the maximum GC yield of 95.47% at 80°C and good reusability. The simple preparation method, good catalytic activity, and reusability of the catalyst shows capability of this catalytic system on an industrial scale." @default.
- W4306408043 created "2022-10-17" @default.
- W4306408043 creator A5000153194 @default.
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- W4306408043 date "2022-10-26" @default.
- W4306408043 modified "2023-10-17" @default.
- W4306408043 title "Modification <scp> g‐C <sub>3</sub> N <sub>4</sub> </scp> by <scp>MgO</scp> and its application for glycerol carbonate synthesis from glycerol and dimethyl carbonate" @default.
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- W4306408043 doi "https://doi.org/10.1002/ep.14007" @default.
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