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- W4306593 abstract "Interaction of gaseous BF3 with the sulfinic acid fluorides 1a,b yields the O-bridged adducts ArS(F)⋯BF3 2a,b (a: Ar= Ph, b:Ar = p-F(C6H4)). Their structure is established by low temperature 13C {1H}-NMR and their reactions. Compounds of type 2 are intermediates in Lewis-acid catalyzed aromatic sulfinylation. Die Einwirkung von BF3-Gas auf die Sulfinsäurefluoride 1a,b führt zu den isolierbaren, O-koordinierten Addukten ArS(F)O⋯BF3 2a,b (a: Ar = Ph, b: Ar = p-F(C6H4)). Ihre Struktur wird aus Tieftemperatur-13C {1H}- NMR-Befunden und dem Reaktionsverhalten abgeleitet. Verbindungen vom Betain- Typ 2 sind Intermediate der “Lewis-Säure”-katalysierten Aromatensulfinylierung." @default.
- W4306593 created "2016-06-24" @default.
- W4306593 creator A5029049855 @default.
- W4306593 date "1982-03-01" @default.
- W4306593 modified "2023-09-30" @default.
- W4306593 title "Isolierbare,o-verbrückte sulfinsäurefluorid/BF3-addukte ArS(F)O⋯BF3[1]" @default.
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- W4306593 doi "https://doi.org/10.1016/s0022-1139(00)84019-1" @default.
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