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- W4306641710 abstract "We describe here the relevant input of Mössbauer spectrometry for the investigation of porous coordination polymers, or metal organic frameworks (MOFs) containing iron cations. We specifically focus on selected examples taken from the long-lasting collaboration between the physicist Jean-Marc Grenèche and French MOF chemists issued from the group of late Gérard Férey. After a brief historical recall, we discuss the expected inputs of Mössbauer spectrometry for chemists working on the synthesis and characterization of new MOFs materials. Two examples are thoroughly described: a series of flexible MOFs presenting the MIL-53 topology, and MOFs based on porphyrin ligands. Through these examples, we will show how the combination of characterization tools (notably X-ray diffraction and Mössbauer spectrometry) is mandatory to achieve a thorough and accurate description of these complex porous hybrid materials and their properties." @default.
- W4306641710 created "2022-10-18" @default.
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- W4306641710 date "2022-10-17" @default.
- W4306641710 modified "2023-09-30" @default.
- W4306641710 title "Insightful contribution of 57Fe Mössbauer spectrometry (and of Jean-Marc Grenèche) to the field of iron metal organic frameworks" @default.
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- W4306641710 doi "https://doi.org/10.1557/s43578-022-00772-2" @default.
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