Matches in SemOpenAlex for { <https://semopenalex.org/work/W4306643155> ?p ?o ?g. }
- W4306643155 abstract "Selective C-H bond activation is one of the most challenging topics for organic reactions. The difficulties arise not only from the high C-H bond dissociation enthalpies but also the existence of multiple equivalent/quasi-equivalent reaction sites in organic molecules. Here, we successfully achieve the selective activation of four quasi-equivalent C-H bonds in a specially designed nitrogen-containing polycyclic hydrocarbon (N-PH). Density functional theory calculations reveal that the adsorption of N-PH on Ag(100) differentiates the activity of the four ortho C(sp3) atoms in the N-heterocycles into two groups, suggesting a selective dehydrogenation, which is demonstrated by sequential-annealing experiments of N-PH/Ag(100). Further annealing leads to the formation of N-doped graphene nanoribbons with partial corannulene motifs, realized by the C-H bond activation process. Our work provides a route of designing precursor molecules with ortho C(sp3) atom in an N-heterocycle to realize surface-induced selective dehydrogenation in quasi-equivalent sites." @default.
- W4306643155 created "2022-10-18" @default.
- W4306643155 creator A5002338651 @default.
- W4306643155 creator A5005092572 @default.
- W4306643155 creator A5017860622 @default.
- W4306643155 creator A5018032683 @default.
- W4306643155 creator A5019978131 @default.
- W4306643155 creator A5023234186 @default.
- W4306643155 creator A5026825791 @default.
- W4306643155 creator A5029588332 @default.
- W4306643155 creator A5034670657 @default.
- W4306643155 creator A5034703672 @default.
- W4306643155 creator A5051056546 @default.
- W4306643155 creator A5052242481 @default.
- W4306643155 creator A5071231802 @default.
- W4306643155 creator A5073621523 @default.
- W4306643155 creator A5074317955 @default.
- W4306643155 creator A5078490750 @default.
- W4306643155 creator A5080306591 @default.
- W4306643155 creator A5083228089 @default.
- W4306643155 creator A5090112031 @default.
- W4306643155 date "2022-10-17" @default.
- W4306643155 modified "2023-10-14" @default.
- W4306643155 title "Selective activation of four quasi-equivalent C–H bonds yields N-doped graphene nanoribbons with partial corannulene motifs" @default.
- W4306643155 cites W1602998205 @default.
- W4306643155 cites W1967445304 @default.
- W4306643155 cites W1969699263 @default.
- W4306643155 cites W1970127494 @default.
- W4306643155 cites W1979544533 @default.
- W4306643155 cites W1994880295 @default.
- W4306643155 cites W2000536749 @default.
- W4306643155 cites W2003193361 @default.
- W4306643155 cites W2024650577 @default.
- W4306643155 cites W2028253542 @default.
- W4306643155 cites W2029316586 @default.
- W4306643155 cites W2050385415 @default.
- W4306643155 cites W2053255767 @default.
- W4306643155 cites W2067433167 @default.
- W4306643155 cites W2077796804 @default.
- W4306643155 cites W2083222334 @default.
- W4306643155 cites W2085106910 @default.
- W4306643155 cites W2090554042 @default.
- W4306643155 cites W2124705248 @default.
- W4306643155 cites W2140372631 @default.
- W4306643155 cites W2152127751 @default.
- W4306643155 cites W2158043072 @default.
- W4306643155 cites W2199686530 @default.
- W4306643155 cites W2285279153 @default.
- W4306643155 cites W2346511364 @default.
- W4306643155 cites W2519591748 @default.
- W4306643155 cites W2586596673 @default.
- W4306643155 cites W2609472088 @default.
- W4306643155 cites W2748116613 @default.
- W4306643155 cites W2766463190 @default.
- W4306643155 cites W2768066850 @default.
- W4306643155 cites W2769730089 @default.
- W4306643155 cites W2777651827 @default.
- W4306643155 cites W2789801316 @default.
- W4306643155 cites W2798195057 @default.
- W4306643155 cites W2885937092 @default.
- W4306643155 cites W2910702629 @default.
- W4306643155 cites W2912359915 @default.
- W4306643155 cites W2921036964 @default.
- W4306643155 cites W2945061531 @default.
- W4306643155 cites W2950656429 @default.
- W4306643155 cites W2967738078 @default.
- W4306643155 cites W3012298836 @default.
- W4306643155 cites W3024517934 @default.
- W4306643155 cites W3106428468 @default.
- W4306643155 cites W3144962882 @default.
- W4306643155 doi "https://doi.org/10.1038/s41467-022-33898-2" @default.
- W4306643155 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36253383" @default.
- W4306643155 hasPublicationYear "2022" @default.
- W4306643155 type Work @default.
- W4306643155 citedByCount "1" @default.
- W4306643155 countsByYear W43066431552023 @default.
- W4306643155 crossrefType "journal-article" @default.
- W4306643155 hasAuthorship W4306643155A5002338651 @default.
- W4306643155 hasAuthorship W4306643155A5005092572 @default.
- W4306643155 hasAuthorship W4306643155A5017860622 @default.
- W4306643155 hasAuthorship W4306643155A5018032683 @default.
- W4306643155 hasAuthorship W4306643155A5019978131 @default.
- W4306643155 hasAuthorship W4306643155A5023234186 @default.
- W4306643155 hasAuthorship W4306643155A5026825791 @default.
- W4306643155 hasAuthorship W4306643155A5029588332 @default.
- W4306643155 hasAuthorship W4306643155A5034670657 @default.
- W4306643155 hasAuthorship W4306643155A5034703672 @default.
- W4306643155 hasAuthorship W4306643155A5051056546 @default.
- W4306643155 hasAuthorship W4306643155A5052242481 @default.
- W4306643155 hasAuthorship W4306643155A5071231802 @default.
- W4306643155 hasAuthorship W4306643155A5073621523 @default.
- W4306643155 hasAuthorship W4306643155A5074317955 @default.
- W4306643155 hasAuthorship W4306643155A5078490750 @default.
- W4306643155 hasAuthorship W4306643155A5080306591 @default.
- W4306643155 hasAuthorship W4306643155A5083228089 @default.
- W4306643155 hasAuthorship W4306643155A5090112031 @default.
- W4306643155 hasBestOaLocation W43066431551 @default.
- W4306643155 hasConcept C102931765 @default.
- W4306643155 hasConcept C119889771 @default.
- W4306643155 hasConcept C147597530 @default.