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- W4306655008 abstract "Aurivillius oxides have been a research focus due to their ferroelectric properties, but by replacing oxide ions by fluoride, divalent magnetic cations can be introduced, giving Bi2MO2F4 (M = Fe, Co, and Ni). Our combined experimental and computational study on Bi2CoO2F4 indicates a low-temperature polar structure of P21ab symmetry (analogous to ferroelectric Bi2WO6) and a ferrimagnetic ground state. These results highlight the potential of Aurivillius oxide-fluorides for multiferroic properties. Our research has also revealed some challenges associated with the reduced tendency for polar displacements in the more ionic fluoride-based systems." @default.
- W4306655008 created "2022-10-18" @default.
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- W4306655008 date "2022-10-17" @default.
- W4306655008 modified "2023-09-27" @default.
- W4306655008 title "Bi<sub>2</sub>CoO<sub>2</sub>F<sub>4</sub>─A Polar, Ferrimagnetic Aurivillius Oxide-Fluoride" @default.
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- W4306655008 doi "https://doi.org/10.1021/acs.chemmater.2c02745" @default.
- W4306655008 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36397835" @default.
- W4306655008 hasPublicationYear "2022" @default.
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