Matches in SemOpenAlex for { <https://semopenalex.org/work/W4306888774> ?p ?o ?g. }
- W4306888774 endingPage "17377" @default.
- W4306888774 startingPage "17370" @default.
- W4306888774 abstract "The transmetalation reaction of picolyl-supported tridentate nacnac germylene monochloride [2,6-iPr2–C6H3NC(Me)CHC(Me)NH(CH2py)]GeCl (1) (py = pyridine) with SnCl2 results in an analogous stannylene chloride (2). The three-coordinated stannylenium cation [{2,6-iPr2–C6H3NC(Me)CHC(Me)NH(CH2py)}Sn]+ with SnCl3– as a counteranion (3) has been generated through the abstraction of chloride ligand from 2 using an additional equivalent of SnCl2. Instead of forming a donor–acceptor complex, 2 undergoes a facile redox transmetalation reaction with Ni(COD)2 (COD = cyclooctadiene) and CuCl to afford analogous nickel and copper complexes [2,6-iPr2–C6H3NC(Me)CHC(Me)NH(CH2py)]MCl [M = Ni (4) and Cu (5)]. The reactions of 4 with potassium tri-sec-butylborohydride (commonly known as K-selectride) and AgSbF6 provide access to monomeric Ni(II) hydride, [2,6-iPr2–C6H3NC(Me)CHC(Me)NH(CH2py)]NiH (6) and a Ni(II) cation, [{2,6-iPr2–C6H3NC(Me)CHC(Me)NH(CH2py)}Ni][SbF6] (7), respectively. 6 was found to be an effective catalyst for the hydroboration of amides." @default.
- W4306888774 created "2022-10-21" @default.
- W4306888774 creator A5022075844 @default.
- W4306888774 creator A5051883016 @default.
- W4306888774 creator A5054599193 @default.
- W4306888774 creator A5084695866 @default.
- W4306888774 creator A5086094822 @default.
- W4306888774 creator A5087496358 @default.
- W4306888774 creator A5090477351 @default.
- W4306888774 date "2022-10-20" @default.
- W4306888774 modified "2023-10-15" @default.
- W4306888774 title "Tridentate NacNac Stabilized Tin and Nickel Complexes: Access to a Monomeric Nickel Hydride and Its Catalytic Application" @default.
- W4306888774 cites W1968940619 @default.
- W4306888774 cites W1971603105 @default.
- W4306888774 cites W1972244400 @default.
- W4306888774 cites W1981908863 @default.
- W4306888774 cites W1983655083 @default.
- W4306888774 cites W1984729923 @default.
- W4306888774 cites W1998468853 @default.
- W4306888774 cites W2002212864 @default.
- W4306888774 cites W2010763248 @default.
- W4306888774 cites W2011042434 @default.
- W4306888774 cites W2046630863 @default.
- W4306888774 cites W2053980317 @default.
- W4306888774 cites W2090895780 @default.
- W4306888774 cites W2093947989 @default.
- W4306888774 cites W2104699219 @default.
- W4306888774 cites W2111118274 @default.
- W4306888774 cites W2133156121 @default.
- W4306888774 cites W2135867276 @default.
- W4306888774 cites W2154482326 @default.
- W4306888774 cites W2319513935 @default.
- W4306888774 cites W2329857382 @default.
- W4306888774 cites W2334786938 @default.
- W4306888774 cites W2417917758 @default.
- W4306888774 cites W2461139757 @default.
- W4306888774 cites W2482078294 @default.
- W4306888774 cites W2589546906 @default.
- W4306888774 cites W2792382614 @default.
- W4306888774 cites W2809207845 @default.
- W4306888774 cites W2903232812 @default.
- W4306888774 cites W2908019343 @default.
- W4306888774 cites W2949720378 @default.
- W4306888774 cites W2990041702 @default.
- W4306888774 cites W3000994196 @default.
- W4306888774 cites W3014364773 @default.
- W4306888774 cites W3045188107 @default.
- W4306888774 cites W3048458888 @default.
- W4306888774 cites W3080804304 @default.
- W4306888774 cites W3111160006 @default.
- W4306888774 cites W3125477770 @default.
- W4306888774 cites W3126377728 @default.
- W4306888774 cites W3154997169 @default.
- W4306888774 cites W3176781043 @default.
- W4306888774 cites W3199432685 @default.
- W4306888774 cites W3209056787 @default.
- W4306888774 cites W3209822059 @default.
- W4306888774 cites W4210386652 @default.
- W4306888774 cites W4210600627 @default.
- W4306888774 cites W4283330430 @default.
- W4306888774 doi "https://doi.org/10.1021/acs.inorgchem.2c03227" @default.
- W4306888774 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36264667" @default.
- W4306888774 hasPublicationYear "2022" @default.
- W4306888774 type Work @default.
- W4306888774 citedByCount "3" @default.
- W4306888774 countsByYear W43068887742023 @default.
- W4306888774 crossrefType "journal-article" @default.
- W4306888774 hasAuthorship W4306888774A5022075844 @default.
- W4306888774 hasAuthorship W4306888774A5051883016 @default.
- W4306888774 hasAuthorship W4306888774A5054599193 @default.
- W4306888774 hasAuthorship W4306888774A5084695866 @default.
- W4306888774 hasAuthorship W4306888774A5086094822 @default.
- W4306888774 hasAuthorship W4306888774A5087496358 @default.
- W4306888774 hasAuthorship W4306888774A5090477351 @default.
- W4306888774 hasConcept C116569031 @default.
- W4306888774 hasConcept C142653250 @default.
- W4306888774 hasConcept C155647269 @default.
- W4306888774 hasConcept C161790260 @default.
- W4306888774 hasConcept C166940927 @default.
- W4306888774 hasConcept C170493617 @default.
- W4306888774 hasConcept C178790620 @default.
- W4306888774 hasConcept C179104552 @default.
- W4306888774 hasConcept C185592680 @default.
- W4306888774 hasConcept C188027245 @default.
- W4306888774 hasConcept C196306401 @default.
- W4306888774 hasConcept C2777961443 @default.
- W4306888774 hasConcept C2779485729 @default.
- W4306888774 hasConcept C504270822 @default.
- W4306888774 hasConcept C521977710 @default.
- W4306888774 hasConcept C544153396 @default.
- W4306888774 hasConcept C55493867 @default.
- W4306888774 hasConceptScore W4306888774C116569031 @default.
- W4306888774 hasConceptScore W4306888774C142653250 @default.
- W4306888774 hasConceptScore W4306888774C155647269 @default.
- W4306888774 hasConceptScore W4306888774C161790260 @default.
- W4306888774 hasConceptScore W4306888774C166940927 @default.
- W4306888774 hasConceptScore W4306888774C170493617 @default.
- W4306888774 hasConceptScore W4306888774C178790620 @default.