Matches in SemOpenAlex for { <https://semopenalex.org/work/W4306898330> ?p ?o ?g. }
- W4306898330 endingPage "20066" @default.
- W4306898330 startingPage "20056" @default.
- W4306898330 abstract "The catalysis by a π-allyl-Co/Ni complex has drawn significant attention recently due to its distinct reactivity in reductive Co/Ni-catalyzed allylation reactions. Despite significant success in reaction development, the critical oxidative addition mechanism to form the π-allyl-Co/Ni complex remains unclear. Herein, we present a study to investigate this process with four catalysis-relevant complexes: Co(MeBPy)Br2, Co(MePhen)Br2, Ni(MeBPy)Br2, and Ni(MePhen)Br2. Enabled by an electroanalytical platform, Co(I)/Ni(I) species were found responsible for the oxidative addition of allyl acetate. Kinetic features of different substrates were characterized through linear free-energy relationship (Hammett-type) studies, statistical modeling, and a DFT computational study. In this process, a coordination-ionization-type transition state was proposed, sharing a similar feature with Pd(0)-mediated oxidative addition in Tsuji-Trost reactions. Computational and ligand structural analysis studies support this mechanism, which should provide key information for next-generation catalyst development." @default.
- W4306898330 created "2022-10-21" @default.
- W4306898330 creator A5005862481 @default.
- W4306898330 creator A5027664472 @default.
- W4306898330 creator A5030184788 @default.
- W4306898330 creator A5042228437 @default.
- W4306898330 creator A5068598679 @default.
- W4306898330 creator A5069844450 @default.
- W4306898330 date "2022-10-20" @default.
- W4306898330 modified "2023-10-17" @default.
- W4306898330 title "Investigating Oxidative Addition Mechanisms of Allylic Electrophiles with Low-Valent Ni/Co Catalysts Using Electroanalytical and Data Science Techniques" @default.
- W4306898330 cites W1964413854 @default.
- W4306898330 cites W1966937884 @default.
- W4306898330 cites W1974003409 @default.
- W4306898330 cites W1977143389 @default.
- W4306898330 cites W1981997364 @default.
- W4306898330 cites W1987073644 @default.
- W4306898330 cites W1987519421 @default.
- W4306898330 cites W1988758147 @default.
- W4306898330 cites W1995808562 @default.
- W4306898330 cites W2031192939 @default.
- W4306898330 cites W2036248708 @default.
- W4306898330 cites W2049095005 @default.
- W4306898330 cites W2051354843 @default.
- W4306898330 cites W2052277449 @default.
- W4306898330 cites W2055790868 @default.
- W4306898330 cites W2074370823 @default.
- W4306898330 cites W2079241446 @default.
- W4306898330 cites W2086395958 @default.
- W4306898330 cites W2093780566 @default.
- W4306898330 cites W2098372510 @default.
- W4306898330 cites W2112003919 @default.
- W4306898330 cites W2136622538 @default.
- W4306898330 cites W2160790360 @default.
- W4306898330 cites W2318270387 @default.
- W4306898330 cites W2319496673 @default.
- W4306898330 cites W2324441431 @default.
- W4306898330 cites W2327819282 @default.
- W4306898330 cites W2331704043 @default.
- W4306898330 cites W2396220592 @default.
- W4306898330 cites W2474488996 @default.
- W4306898330 cites W2605975259 @default.
- W4306898330 cites W2783050535 @default.
- W4306898330 cites W2896961857 @default.
- W4306898330 cites W2907148463 @default.
- W4306898330 cites W2907890304 @default.
- W4306898330 cites W2943535788 @default.
- W4306898330 cites W2945033219 @default.
- W4306898330 cites W2950584178 @default.
- W4306898330 cites W2952534172 @default.
- W4306898330 cites W2966790579 @default.
- W4306898330 cites W2973096734 @default.
- W4306898330 cites W2979452426 @default.
- W4306898330 cites W2985146327 @default.
- W4306898330 cites W2987022071 @default.
- W4306898330 cites W3005255628 @default.
- W4306898330 cites W3005351445 @default.
- W4306898330 cites W3040707242 @default.
- W4306898330 cites W3047140557 @default.
- W4306898330 cites W3080857928 @default.
- W4306898330 cites W3106943604 @default.
- W4306898330 cites W3110724411 @default.
- W4306898330 cites W3129515013 @default.
- W4306898330 cites W3129874447 @default.
- W4306898330 cites W3137642175 @default.
- W4306898330 cites W3138833789 @default.
- W4306898330 cites W3154016589 @default.
- W4306898330 cites W3171429184 @default.
- W4306898330 cites W3178288747 @default.
- W4306898330 cites W3189719592 @default.
- W4306898330 cites W3194661976 @default.
- W4306898330 cites W3204584645 @default.
- W4306898330 cites W4200102223 @default.
- W4306898330 cites W4206889351 @default.
- W4306898330 cites W4213251682 @default.
- W4306898330 cites W4220829722 @default.
- W4306898330 cites W4221049251 @default.
- W4306898330 cites W4221130516 @default.
- W4306898330 cites W4223515774 @default.
- W4306898330 cites W4281482094 @default.
- W4306898330 cites W4282046116 @default.
- W4306898330 cites W4283781399 @default.
- W4306898330 cites W4285076944 @default.
- W4306898330 doi "https://doi.org/10.1021/jacs.2c09120" @default.
- W4306898330 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36265077" @default.
- W4306898330 hasPublicationYear "2022" @default.
- W4306898330 type Work @default.
- W4306898330 citedByCount "7" @default.
- W4306898330 countsByYear W43068983302022 @default.
- W4306898330 countsByYear W43068983302023 @default.
- W4306898330 crossrefType "journal-article" @default.
- W4306898330 hasAuthorship W4306898330A5005862481 @default.
- W4306898330 hasAuthorship W4306898330A5027664472 @default.
- W4306898330 hasAuthorship W4306898330A5030184788 @default.
- W4306898330 hasAuthorship W4306898330A5042228437 @default.
- W4306898330 hasAuthorship W4306898330A5068598679 @default.
- W4306898330 hasAuthorship W4306898330A5069844450 @default.
- W4306898330 hasConcept C106773901 @default.