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- W4306922014 abstract "Abstract AIBN (2,2′-azobisisobutyronitrile) and analogues are readily available chemical reagents that are widely used as free-radical initiators of polymer chemistry. Importantly, AIBN and derivatives are also safe and efficient (alkyl)cyano sources for synthesizing cyano-containing scaffolds. In the past decades, synthetic strategies using AIBN and derivatives as radical sources have attracted increasing attention from the synthetic community. This review will provide a valuable tool for understanding the importance of AIBN and derivatives in the area of synthetic chemistry. In this context, we present a comprehensive review that guides readers through the developments in AIBN chemistry over the past five years from several aspects. 1 Introduction 2 Radical Addition onto Alkenes or Alkynes using AIBN as Cyanoalkyl Radical 3 Dehydrogenated, decarboxylated cyano-alkylation by using AIBN and analogues 4 Synthesis of Ketone and its Derivatives with AIBN and Analogues as Carbonyl Source 5 Construction of Multi-ring Skeletons in the Presence of AIBN and Analogues 6 Direct Application as Cyano (CN) Source in Cyanation Reactions 7 Conclusions" @default.
- W4306922014 created "2022-10-21" @default.
- W4306922014 creator A5040655982 @default.
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- W4306922014 date "2022-10-20" @default.
- W4306922014 modified "2023-10-16" @default.
- W4306922014 title "Recent Advances on Radical-Mediated Cyanoalkylation/Cyanation using AIBN and Analogues as the Radical Sources" @default.
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- W4306922014 doi "https://doi.org/10.1055/a-1965-3028" @default.
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