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- W4306970596 abstract "Bicyclo[1.1.1]pentylamines (BPCAs), emerging as sp 3 -rich surrogates for aniline and its derivatives, demonstrate unique structural features and physicochemical profiles in medicinal and synthetic chemistry. In recent years, compared with conventional synthetic approaches, the rapid development of radical chemistry enables the assembly of valuable bicyclo[1.1.1]pentylamines scaffold directly through the amination transformation of highly strained [1.1.1]propellane. In this review, we concisely summarize the emerging role of radical chemistry in the construction of BCPAs motif, highlighting two different and powerful radical-involved strategies including C -centered and N -centered radical pathways under appropriate conditions. The future direction concerning BCPAs is also discussed at the end of this review, which aims to provide some inspiration for the research of this promising project." @default.
- W4306970596 created "2022-10-22" @default.
- W4306970596 creator A5000510528 @default.
- W4306970596 creator A5004021884 @default.
- W4306970596 creator A5027563473 @default.
- W4306970596 creator A5034761662 @default.
- W4306970596 creator A5054925940 @default.
- W4306970596 creator A5056438507 @default.
- W4306970596 creator A5060805738 @default.
- W4306970596 creator A5069555479 @default.
- W4306970596 date "2022-10-21" @default.
- W4306970596 modified "2023-10-15" @default.
- W4306970596 title "The emerging role of radical chemistry in the amination transformation of highly strained [1.1.1]propellane: Bicyclo[1.1.1]pentylamine as bioisosteres of anilines" @default.
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