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- W4307029592 abstract "• The Pre-Eifelian paleosol on rhyolite demonstrates surprisingly deep development. • Rhyolite contains allochthonous substituted by pyrite inclusions of nematophyte. • Pyrite oxidation drives the acid sulfate paleosol development. • Gypseous acid sulfate paleosol was developed under warm humid climate. During Late Devonian Voronezh Land was one of the main volcanic centers of Central Devonian Field. Earlier eruptions on the given territory have not been documented. This paper presents the detailed multidisciplinary study of the Pre-Eifelian paleosol developed from rhyolite lava deposited on the contact with the Proterozoic basement in Shkurlat granite quarry (Voronezh region, Russia). Discovered paleosol includes abundant coalified and partly substituted by pyrite allochthonous remnants of Nematasketum and Prototaxites. Main part of them had an outstanding preservation of tissues. Along with typical for rhyolite a quartz dominance, paleosol contains in situ developed kaolinite, gypsum, goethite, jarosite. Abundant Fe-nodules concentrated in the second half part of the shallow (∼50 cm) paleosol profile are composed of gypsum, goethite and metastable Fe-sulfates - jarosite and voltaite. Based on a complex of analytical characteristics, the discovered paleosol was attributed to acidic sulfate soil. The development of paleosol was initiated by pyrite oxidation which played the role of trigger. Being gypseous, paleosol bears the characteristics which are typical for paleosol of humid type. Based on geochemical data (CIA, CIA-K, PWI indexes) the obtained climatic parameters correspond to a subtropical climate with MAP 1200–1300 mm and MAT ∼ 17 °C." @default.
- W4307029592 created "2022-10-22" @default.
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- W4307029592 date "2023-01-01" @default.
- W4307029592 modified "2023-09-23" @default.
- W4307029592 title "Sulfide oxidation as a trigger for rhyolite weathering and paleosol formation in Devonian (Voronezh High, South Russia)" @default.
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- W4307029592 doi "https://doi.org/10.1016/j.catena.2022.106712" @default.
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