Matches in SemOpenAlex for { <https://semopenalex.org/work/W4307032085> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W4307032085 endingPage "7982" @default.
- W4307032085 startingPage "7978" @default.
- W4307032085 abstract "We report a new anionic cascade for assembling 2,4-substituted benzoate esters in one pot from racemic β-fluoro-substituted conjugated tert-butylsulfinyl imines and 3-substituted methyl 2-butenoates. Dienolate formation triggers a Mannich addition followed by an amino-Cope like rearrangement, which results in immediate elimination of fluoride by a lithiated enamine. The newly formed 1,4-diene intermediate contains a highly acidic proton which is spontaneously deprotonated, leading to a facile intramolecular cyclization followed by sulfinamide group elimination and aromatization." @default.
- W4307032085 created "2022-10-23" @default.
- W4307032085 creator A5008495170 @default.
- W4307032085 creator A5089121991 @default.
- W4307032085 date "2022-10-21" @default.
- W4307032085 modified "2023-10-17" @default.
- W4307032085 title "Anionic Amino-Cope Rearrangement Cascade Synthesis of 2,4-Substituted Benzoate Esters from Acyclic Building Blocks" @default.
- W4307032085 cites W2002845815 @default.
- W4307032085 cites W2003045768 @default.
- W4307032085 cites W2009445872 @default.
- W4307032085 cites W2030400224 @default.
- W4307032085 cites W2546979609 @default.
- W4307032085 cites W2752088029 @default.
- W4307032085 cites W2765558401 @default.
- W4307032085 cites W2909275830 @default.
- W4307032085 cites W2986779843 @default.
- W4307032085 cites W3155107246 @default.
- W4307032085 cites W3183201993 @default.
- W4307032085 cites W4212817401 @default.
- W4307032085 cites W4213152682 @default.
- W4307032085 cites W2040224210 @default.
- W4307032085 doi "https://doi.org/10.1021/acs.orglett.2c03134" @default.
- W4307032085 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36268999" @default.
- W4307032085 hasPublicationYear "2022" @default.
- W4307032085 type Work @default.
- W4307032085 citedByCount "1" @default.
- W4307032085 countsByYear W43070320852023 @default.
- W4307032085 crossrefType "journal-article" @default.
- W4307032085 hasAuthorship W4307032085A5008495170 @default.
- W4307032085 hasAuthorship W4307032085A5089121991 @default.
- W4307032085 hasConcept C118629725 @default.
- W4307032085 hasConcept C145148216 @default.
- W4307032085 hasConcept C155647269 @default.
- W4307032085 hasConcept C161790260 @default.
- W4307032085 hasConcept C176933379 @default.
- W4307032085 hasConcept C178790620 @default.
- W4307032085 hasConcept C185592680 @default.
- W4307032085 hasConcept C2776378156 @default.
- W4307032085 hasConcept C2778733088 @default.
- W4307032085 hasConcept C2779325354 @default.
- W4307032085 hasConcept C71240020 @default.
- W4307032085 hasConcept C75079739 @default.
- W4307032085 hasConceptScore W4307032085C118629725 @default.
- W4307032085 hasConceptScore W4307032085C145148216 @default.
- W4307032085 hasConceptScore W4307032085C155647269 @default.
- W4307032085 hasConceptScore W4307032085C161790260 @default.
- W4307032085 hasConceptScore W4307032085C176933379 @default.
- W4307032085 hasConceptScore W4307032085C178790620 @default.
- W4307032085 hasConceptScore W4307032085C185592680 @default.
- W4307032085 hasConceptScore W4307032085C2776378156 @default.
- W4307032085 hasConceptScore W4307032085C2778733088 @default.
- W4307032085 hasConceptScore W4307032085C2779325354 @default.
- W4307032085 hasConceptScore W4307032085C71240020 @default.
- W4307032085 hasConceptScore W4307032085C75079739 @default.
- W4307032085 hasFunder F4320337393 @default.
- W4307032085 hasIssue "43" @default.
- W4307032085 hasLocation W43070320851 @default.
- W4307032085 hasLocation W43070320852 @default.
- W4307032085 hasOpenAccess W4307032085 @default.
- W4307032085 hasPrimaryLocation W43070320851 @default.
- W4307032085 hasRelatedWork W1991725244 @default.
- W4307032085 hasRelatedWork W1999887477 @default.
- W4307032085 hasRelatedWork W2058529431 @default.
- W4307032085 hasRelatedWork W2065109056 @default.
- W4307032085 hasRelatedWork W2069972256 @default.
- W4307032085 hasRelatedWork W2949522609 @default.
- W4307032085 hasRelatedWork W2949928855 @default.
- W4307032085 hasRelatedWork W2952183671 @default.
- W4307032085 hasRelatedWork W4307032085 @default.
- W4307032085 hasRelatedWork W4316662369 @default.
- W4307032085 hasVolume "24" @default.
- W4307032085 isParatext "false" @default.
- W4307032085 isRetracted "false" @default.
- W4307032085 workType "article" @default.