Matches in SemOpenAlex for { <https://semopenalex.org/work/W4307218737> ?p ?o ?g. }
- W4307218737 endingPage "2408" @default.
- W4307218737 startingPage "2400" @default.
- W4307218737 abstract "Phenolic compounds can be oxidized by manganese oxides in the subsurface or during passive treatment of stormwater runoff and wastewater effluent. Contaminated waters may contain a complex mixture of phenolic compounds, and these mixtures may have additive, synergistic, or antagonistic toxicological effects. However, the effects of such mixtures on the rates and mechanisms of phenol oxidation by manganese oxides are not well understood. This study addresses this knowledge gap by determining pseudo-first-order oxidation rates and oxidation mechanisms for four phenols reacted with δ-MnO2 in varying mixtures. Oxidation rates of electron transfer-limited phenols (i.e., triclosan, resorcinol, bisphenol A) are inhibited in mixtures. This inhibition, as well as the observed decrease in sorption, is consistent with competition between phenols occurring near the Mn surface. In contrast, the oxidation rate and extent of sorption for sorption-limited 4,4′-biphenol are enhanced in mixtures. The rate enhancement is partially driven by indirect oxidation through radical-mediated reactions, likely from phenoxy radicals produced when electron transfer-limited phenols react with δ-MnO2. These findings demonstrate that mixtures have a large impact on phenol oxidation by manganese oxides, as the electron transfer-limited phenols are inhibited due to competition interactions and the sorption-limited phenol has increased oxidation rates due to indirect oxidation by radicals and enhanced sorption." @default.
- W4307218737 created "2022-10-30" @default.
- W4307218737 creator A5013111448 @default.
- W4307218737 creator A5068682577 @default.
- W4307218737 creator A5091083675 @default.
- W4307218737 date "2022-10-25" @default.
- W4307218737 modified "2023-10-17" @default.
- W4307218737 title "Enhancement and Inhibition of Oxidation in Phenolic Compound Mixtures with Manganese Oxides" @default.
- W4307218737 cites W1852706488 @default.
- W4307218737 cites W1974091253 @default.
- W4307218737 cites W1976412837 @default.
- W4307218737 cites W1980361407 @default.
- W4307218737 cites W1986246969 @default.
- W4307218737 cites W1986327441 @default.
- W4307218737 cites W1995089473 @default.
- W4307218737 cites W1998482184 @default.
- W4307218737 cites W2000153282 @default.
- W4307218737 cites W2022023971 @default.
- W4307218737 cites W2022452244 @default.
- W4307218737 cites W2026615943 @default.
- W4307218737 cites W2027894833 @default.
- W4307218737 cites W2033761422 @default.
- W4307218737 cites W2034916099 @default.
- W4307218737 cites W2041291423 @default.
- W4307218737 cites W2044723574 @default.
- W4307218737 cites W2048628028 @default.
- W4307218737 cites W2062292859 @default.
- W4307218737 cites W2065829273 @default.
- W4307218737 cites W2068282811 @default.
- W4307218737 cites W2073173544 @default.
- W4307218737 cites W2076419115 @default.
- W4307218737 cites W2085864457 @default.
- W4307218737 cites W2086732216 @default.
- W4307218737 cites W2090988300 @default.
- W4307218737 cites W2091932095 @default.
- W4307218737 cites W2092937320 @default.
- W4307218737 cites W2094531425 @default.
- W4307218737 cites W2136979605 @default.
- W4307218737 cites W2137171441 @default.
- W4307218737 cites W2142660543 @default.
- W4307218737 cites W2145192726 @default.
- W4307218737 cites W2323937288 @default.
- W4307218737 cites W2325496959 @default.
- W4307218737 cites W2332656966 @default.
- W4307218737 cites W2334827312 @default.
- W4307218737 cites W2345538504 @default.
- W4307218737 cites W2510451947 @default.
- W4307218737 cites W2526000718 @default.
- W4307218737 cites W2526141653 @default.
- W4307218737 cites W2558623862 @default.
- W4307218737 cites W2586429233 @default.
- W4307218737 cites W2591477854 @default.
- W4307218737 cites W2601433065 @default.
- W4307218737 cites W2604358569 @default.
- W4307218737 cites W2605441478 @default.
- W4307218737 cites W2609566010 @default.
- W4307218737 cites W2609786205 @default.
- W4307218737 cites W2611265199 @default.
- W4307218737 cites W2756295038 @default.
- W4307218737 cites W2767483900 @default.
- W4307218737 cites W2795200791 @default.
- W4307218737 cites W2803462082 @default.
- W4307218737 cites W2804094673 @default.
- W4307218737 cites W2889167521 @default.
- W4307218737 cites W2902206777 @default.
- W4307218737 cites W2919108125 @default.
- W4307218737 cites W2923748216 @default.
- W4307218737 cites W2934558871 @default.
- W4307218737 cites W2994732185 @default.
- W4307218737 cites W2995626295 @default.
- W4307218737 cites W3003868557 @default.
- W4307218737 cites W3044851268 @default.
- W4307218737 cites W3087285353 @default.
- W4307218737 cites W3127742350 @default.
- W4307218737 cites W3193419363 @default.
- W4307218737 cites W4205820618 @default.
- W4307218737 cites W4210498951 @default.
- W4307218737 cites W4280501565 @default.
- W4307218737 doi "https://doi.org/10.1021/acsestwater.2c00261" @default.
- W4307218737 hasPublicationYear "2022" @default.
- W4307218737 type Work @default.
- W4307218737 citedByCount "1" @default.
- W4307218737 countsByYear W43072187372023 @default.
- W4307218737 crossrefType "journal-article" @default.
- W4307218737 hasAuthorship W4307218737A5013111448 @default.
- W4307218737 hasAuthorship W4307218737A5068682577 @default.
- W4307218737 hasAuthorship W4307218737A5091083675 @default.
- W4307218737 hasConcept C139066938 @default.
- W4307218737 hasConcept C150394285 @default.
- W4307218737 hasConcept C178790620 @default.
- W4307218737 hasConcept C179104552 @default.
- W4307218737 hasConcept C185592680 @default.
- W4307218737 hasConcept C2777702071 @default.
- W4307218737 hasConcept C2777728882 @default.
- W4307218737 hasConcept C2780016452 @default.
- W4307218737 hasConcept C528890316 @default.
- W4307218737 hasConcept C58445606 @default.
- W4307218737 hasConceptScore W4307218737C139066938 @default.