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• W4307229713 abstract "We achieved a divergent synthesis of isoquinolin-2(1H)-yl-acetamides (16 examples, up to 90% yields) and regioselective isoindolin-2-yl-acetamides (14 examples, up to 93% yields) in moderate to good yields by reacting various substituted ethanones or terminal alkynes with Ugi-4CR intermediates via an ammonia-Ugi-4CR/Copper(I)-catalyzed annulation sequence reaction. The same intermediate thus gives 2D distant but 3D closely related scaffolds, which can be of high interest in exploiting chemistry space on a receptor. The scopes and limitations of these efficient sequence reactions are described, as well as gram-scale synthesis." @default.
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• W4307229713 date "2022-10-25" @default.
• W4307229713 modified "2023-09-26" @default.
• W4307229713 title "Access to Isoquinolin-2(1<i>H</i>)-yl-acetamides and Isoindolin-2-yl-acetamides from a Common MCR Precursor" @default.
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• W4307229713 doi "https://doi.org/10.1021/acs.joc.2c01905" @default.
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