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- W4307264865 abstract "An operationally convenient Zn-catalyzed synthesis of alcohols by the reduction of aldehydes, ketones, and α,β-unsaturated aldehydes/ketones is reported. It is a rare example of using mild and sustainable HBpin as a reductant for catalytic reduction of carbonyl compounds in the absence of acid or base as hydrolysis reagent. The reaction is upscalable and proceeds in high selectivity without the formation of boronate ester by-products, and tolerates sensitive functionalities, such as iodo, bromo, chloro, fluoro, nitro, trifluoromethyl, aminomethyl, alkynyl, and amide. The Zn(OAc)2/HBpin combination has been also proved to be chemoselective for the C=N reduction of imine analogs." @default.
- W4307264865 created "2022-10-31" @default.
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- W4307264865 date "2022-10-21" @default.
- W4307264865 modified "2023-10-02" @default.
- W4307264865 title "Zn-Catalyzed Regioselective and Chemoselective Reduction of Aldehydes, Ketones and Imines" @default.
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- W4307264865 doi "https://doi.org/10.3390/ijms232012679" @default.
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