Matches in SemOpenAlex for { <https://semopenalex.org/work/W4307291005> ?p ?o ?g. }
- W4307291005 abstract "The Laporte rule dictates that one- and two-photon absorption spectra of inversion-symmetric molecules should display alternatively forbidden electronic transitions; however, for organic fluorophores, drawing clear distinction between the symmetric- and non-inversion symmetric two-photon spectra is often obscured due to prevalent vibronic interactions. We take advantage of consecutive single- and double-protonation to break and then reconstitute inversion symmetry in a nominally symmetric diketopyrrolopyrrole, causing large changes in two-photon absorption. By performing detailed one- and two-photon titration experiments, with supporting quantum-chemical model calculations, we explain how certain low-frequency vibrational modes may lead to apparent deviations from the strict Laporte rule. As a result, the system may be indeed considered as an on-off-on inversion symmetry switch, opening new avenues for two-photon sensing applications." @default.
- W4307291005 created "2022-10-31" @default.
- W4307291005 creator A5001460713 @default.
- W4307291005 creator A5034497047 @default.
- W4307291005 creator A5042543154 @default.
- W4307291005 creator A5044722268 @default.
- W4307291005 creator A5045133170 @default.
- W4307291005 creator A5048766478 @default.
- W4307291005 creator A5051564881 @default.
- W4307291005 creator A5052256768 @default.
- W4307291005 creator A5063867141 @default.
- W4307291005 creator A5065884002 @default.
- W4307291005 creator A5071373908 @default.
- W4307291005 creator A5082524492 @default.
- W4307291005 creator A5002099850 @default.
- W4307291005 date "2022-11-22" @default.
- W4307291005 modified "2023-10-17" @default.
- W4307291005 title "On‐off‐on Control of Molecular Inversion Symmetry via Multi‐stage Protonation: Elucidating Vibronic Laporte Rule" @default.
- W4307291005 cites W1753434211 @default.
- W4307291005 cites W1972622624 @default.
- W4307291005 cites W1978909544 @default.
- W4307291005 cites W1979022843 @default.
- W4307291005 cites W1980023437 @default.
- W4307291005 cites W1984960598 @default.
- W4307291005 cites W1988493742 @default.
- W4307291005 cites W1993774306 @default.
- W4307291005 cites W1995997812 @default.
- W4307291005 cites W2003668889 @default.
- W4307291005 cites W2010234682 @default.
- W4307291005 cites W2010411760 @default.
- W4307291005 cites W2014215384 @default.
- W4307291005 cites W2016093232 @default.
- W4307291005 cites W2017736507 @default.
- W4307291005 cites W2020586973 @default.
- W4307291005 cites W2032579267 @default.
- W4307291005 cites W2037152936 @default.
- W4307291005 cites W2041182533 @default.
- W4307291005 cites W2048048090 @default.
- W4307291005 cites W2049089158 @default.
- W4307291005 cites W2050044028 @default.
- W4307291005 cites W2062852634 @default.
- W4307291005 cites W2094729894 @default.
- W4307291005 cites W2102146946 @default.
- W4307291005 cites W2309283660 @default.
- W4307291005 cites W2338596881 @default.
- W4307291005 cites W2396843170 @default.
- W4307291005 cites W2581333905 @default.
- W4307291005 cites W2697036071 @default.
- W4307291005 cites W2759491940 @default.
- W4307291005 cites W2761259848 @default.
- W4307291005 cites W2795023310 @default.
- W4307291005 cites W3007608016 @default.
- W4307291005 doi "https://doi.org/10.1002/ange.202212581" @default.
- W4307291005 hasPublicationYear "2022" @default.
- W4307291005 type Work @default.
- W4307291005 citedByCount "0" @default.
- W4307291005 crossrefType "journal-article" @default.
- W4307291005 hasAuthorship W4307291005A5001460713 @default.
- W4307291005 hasAuthorship W4307291005A5002099850 @default.
- W4307291005 hasAuthorship W4307291005A5034497047 @default.
- W4307291005 hasAuthorship W4307291005A5042543154 @default.
- W4307291005 hasAuthorship W4307291005A5044722268 @default.
- W4307291005 hasAuthorship W4307291005A5045133170 @default.
- W4307291005 hasAuthorship W4307291005A5048766478 @default.
- W4307291005 hasAuthorship W4307291005A5051564881 @default.
- W4307291005 hasAuthorship W4307291005A5052256768 @default.
- W4307291005 hasAuthorship W4307291005A5063867141 @default.
- W4307291005 hasAuthorship W4307291005A5065884002 @default.
- W4307291005 hasAuthorship W4307291005A5071373908 @default.
- W4307291005 hasAuthorship W4307291005A5082524492 @default.
- W4307291005 hasBestOaLocation W43072910052 @default.
- W4307291005 hasConcept C109007969 @default.
- W4307291005 hasConcept C117137515 @default.
- W4307291005 hasConcept C119824511 @default.
- W4307291005 hasConcept C121332964 @default.
- W4307291005 hasConcept C145148216 @default.
- W4307291005 hasConcept C151730666 @default.
- W4307291005 hasConcept C159317903 @default.
- W4307291005 hasConcept C159467904 @default.
- W4307291005 hasConcept C182498248 @default.
- W4307291005 hasConcept C184779094 @default.
- W4307291005 hasConcept C185592680 @default.
- W4307291005 hasConcept C188914724 @default.
- W4307291005 hasConcept C1893757 @default.
- W4307291005 hasConcept C2524010 @default.
- W4307291005 hasConcept C26873012 @default.
- W4307291005 hasConcept C2779886137 @default.
- W4307291005 hasConcept C30095370 @default.
- W4307291005 hasConcept C32909587 @default.
- W4307291005 hasConcept C33923547 @default.
- W4307291005 hasConcept C41999313 @default.
- W4307291005 hasConcept C4839761 @default.
- W4307291005 hasConcept C62520636 @default.
- W4307291005 hasConcept C86803240 @default.
- W4307291005 hasConcept C88407732 @default.
- W4307291005 hasConceptScore W4307291005C109007969 @default.
- W4307291005 hasConceptScore W4307291005C117137515 @default.
- W4307291005 hasConceptScore W4307291005C119824511 @default.
- W4307291005 hasConceptScore W4307291005C121332964 @default.
- W4307291005 hasConceptScore W4307291005C145148216 @default.