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- W4307336586 abstract "We describe our efforts toward the total synthesis of the natural product elisabethin A. The first route was guided by the proposed biosynthesis, assembling the 6,6-ring system before forming the five-membered ring including the quaternary carbon. The second approach includes a high yielding cyclization under Mitsunobu conditions as a key step. It allowed the preparation of an unusual and highly functionalized bicyclic 6,5-spiro compound. Both routes share a common advanced precursor obtained from an underdeveloped Claisen rearrangement of an aryl dienyl ether." @default.
- W4307336586 created "2022-10-31" @default.
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- W4307336586 date "2022-10-25" @default.
- W4307336586 modified "2023-10-14" @default.
- W4307336586 title "Efforts toward the Total Synthesis of Elisabethin A" @default.
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- W4307336586 doi "https://doi.org/10.1021/acs.joc.2c01914" @default.
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