Matches in SemOpenAlex for { <https://semopenalex.org/work/W430734927> ?p ?o ?g. }
- W430734927 endingPage "193" @default.
- W430734927 startingPage "119" @default.
- W430734927 abstract "The selective catalytic activation/functionalization of sp2 C–H bonds is expected to improve synthesis methods by better step number and atom economy. This chapter describes the recent achievements of ruthenium(II) catalysed transformations of sp2 C–H bonds for cross-coupled C–C bond formation. First arylation and heteroarylation with aromatic halides of a variety of (hetero)arenes, that are directed at ortho position by heterocycle or imine groups, are presented. The role of carboxylate partners is shown for Ru(II) catalysts that are able to operate profitably in water and to selectively produce diarylated or monoarylated products. The alkylation of (hetero)arenes with primary and secondary alkylhalides, and by hydroarylation of alkene C=C bonds is presented. The recent access to functional alkenes via oxidative dehydrogenative functionalization of C–H bonds with alkenes first, and then with alkynes, is shown to be catalysed by a Ru(II) species associated with a silver salt in the presence of an oxidant such as Cu(OAc)2. Finally the catalytic oxidative annulations with alkynes to rapidly form a variety of heterocycles are described by initial activation of C–H followed by that of N–H or O–H bonds and by formation of a second C–C bond on reaction with C=O, C=N, and sp3 C–H bonds. Most catalytic cycles leading from C–H to C–C bond are discussed." @default.
- W430734927 created "2016-06-24" @default.
- W430734927 creator A5029695887 @default.
- W430734927 creator A5048204818 @default.
- W430734927 date "2014-01-01" @default.
- W430734927 modified "2023-10-14" @default.
- W430734927 title "Ruthenium(II)-Catalysed sp2 C–H Bond Functionalization by C–C Bond Formation" @default.
- W430734927 cites W1492514839 @default.
- W430734927 cites W1661072425 @default.
- W430734927 cites W1964564850 @default.
- W430734927 cites W1964602959 @default.
- W430734927 cites W1964862350 @default.
- W430734927 cites W1966363887 @default.
- W430734927 cites W1966469755 @default.
- W430734927 cites W1967216634 @default.
- W430734927 cites W1968018529 @default.
- W430734927 cites W1968020157 @default.
- W430734927 cites W1969116910 @default.
- W430734927 cites W1970745899 @default.
- W430734927 cites W1974001124 @default.
- W430734927 cites W1977126194 @default.
- W430734927 cites W1978890358 @default.
- W430734927 cites W1981606667 @default.
- W430734927 cites W1981612998 @default.
- W430734927 cites W1982732047 @default.
- W430734927 cites W1983245845 @default.
- W430734927 cites W1985733865 @default.
- W430734927 cites W1985900609 @default.
- W430734927 cites W1987072050 @default.
- W430734927 cites W1987690437 @default.
- W430734927 cites W1988513403 @default.
- W430734927 cites W1989982603 @default.
- W430734927 cites W1990311443 @default.
- W430734927 cites W1992740385 @default.
- W430734927 cites W1993495773 @default.
- W430734927 cites W1994554448 @default.
- W430734927 cites W1995110816 @default.
- W430734927 cites W1995347332 @default.
- W430734927 cites W1995398990 @default.
- W430734927 cites W1999746868 @default.
- W430734927 cites W2000844227 @default.
- W430734927 cites W2001526711 @default.
- W430734927 cites W2001986189 @default.
- W430734927 cites W2003876494 @default.
- W430734927 cites W2004853801 @default.
- W430734927 cites W2005172136 @default.
- W430734927 cites W2005661768 @default.
- W430734927 cites W2006666898 @default.
- W430734927 cites W2007523189 @default.
- W430734927 cites W2008042362 @default.
- W430734927 cites W2011352946 @default.
- W430734927 cites W2013673340 @default.
- W430734927 cites W2014264279 @default.
- W430734927 cites W2018301329 @default.
- W430734927 cites W2018387626 @default.
- W430734927 cites W2019406168 @default.
- W430734927 cites W2019745502 @default.
- W430734927 cites W2020596486 @default.
- W430734927 cites W2022696812 @default.
- W430734927 cites W2024536147 @default.
- W430734927 cites W2024983608 @default.
- W430734927 cites W2025131705 @default.
- W430734927 cites W2025150756 @default.
- W430734927 cites W2025968736 @default.
- W430734927 cites W2026688013 @default.
- W430734927 cites W2026905256 @default.
- W430734927 cites W2026915412 @default.
- W430734927 cites W2030462314 @default.
- W430734927 cites W2030768159 @default.
- W430734927 cites W2031385880 @default.
- W430734927 cites W2031580869 @default.
- W430734927 cites W2031757629 @default.
- W430734927 cites W2033753805 @default.
- W430734927 cites W2034098953 @default.
- W430734927 cites W2036044855 @default.
- W430734927 cites W2039565112 @default.
- W430734927 cites W2043625407 @default.
- W430734927 cites W2045942183 @default.
- W430734927 cites W2046134183 @default.
- W430734927 cites W2047176727 @default.
- W430734927 cites W2049146775 @default.
- W430734927 cites W2050791488 @default.
- W430734927 cites W2051778076 @default.
- W430734927 cites W2053132245 @default.
- W430734927 cites W2057048965 @default.
- W430734927 cites W2059672882 @default.
- W430734927 cites W2060621598 @default.
- W430734927 cites W2060953989 @default.
- W430734927 cites W2061343703 @default.
- W430734927 cites W2062723832 @default.
- W430734927 cites W2066309940 @default.
- W430734927 cites W2067326130 @default.
- W430734927 cites W2067433167 @default.
- W430734927 cites W2068195780 @default.
- W430734927 cites W2068589900 @default.
- W430734927 cites W2068749447 @default.
- W430734927 cites W2070490884 @default.
- W430734927 cites W2070766834 @default.