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- W4307357975 abstract "Herein, we report a metal-free protocol for the activation of nitrile towards the nucleophilic addition and subsequent annulation under an aqueous medium for the first time. The protocol divulges an efficient route for the construction of diversified aminated isoquinolines. Differently substituted primary as well as secondary amines underwent the reaction in a highly regioselective manner. The reaction is operationally simple, shows high functional group tolerance, easier modification of well-known drugs, and successfully extended to gram-scale synthesis." @default.
- W4307357975 created "2022-10-31" @default.
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- W4307357975 date "2022-10-26" @default.
- W4307357975 modified "2023-09-24" @default.
- W4307357975 title "Metal-free construction of aminated isoquinoline frameworks from 2-(2-oxo-2-arylethyl) benzonitrile in an aqueous medium" @default.
- W4307357975 doi "https://doi.org/10.26434/chemrxiv-2022-9t28v" @default.
- W4307357975 hasPublicationYear "2022" @default.
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