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- W4307429312 endingPage "20213" @default.
- W4307429312 startingPage "20207" @default.
- W4307429312 abstract "Synthesis of bicyclic scaffolds has attracted growing interest because they are of high importance in modern pharmaceutical development. Here we report a strategy to access polysubstituted 2-oxabicyclo[2.1.1]hexanes in a single operation from readily accessible benzoylformate esters and bicyclo[1.1.0]butanes via visible-light-induced triplet energy transfer catalysis. The process is proposed to involve a formal [2π + 2σ] photocycloaddition/backbone C-H abstraction/aryl group migration sequence. A diverse range of (hetero)aryl groups successfully underwent migration to the backbone (C2) position to provide previously inaccessible bicyclic molecules, and the ester group of the product can serve as a handle for downstream manipulation, thus offering opportunities to rapidly build up molecular complexity and access new sp3-rich chemical space." @default.
- W4307429312 created "2022-11-01" @default.
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- W4307429312 date "2022-10-27" @default.
- W4307429312 modified "2023-10-11" @default.
- W4307429312 title "Synthesis of Polysubstituted 2-Oxabicyclo[2.1.1]hexanes via Visible-Light-Induced Energy Transfer" @default.
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- W4307429312 doi "https://doi.org/10.1021/jacs.2c09248" @default.
- W4307429312 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36301322" @default.
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