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- W4307431063 endingPage "20248" @default.
- W4307431063 startingPage "20243" @default.
- W4307431063 abstract "The synthesis and reactivity of an ambiphilic iridium complex IrCl(PPh3)(L1) (1; L1 = P(N(o-N(2-pyridyl)C6H4)2)) featuring a chelating nontrigonal phosphorus triamide ligand is reported. The tandem Lewis basic Ir and Lewis acidic P of 1 achieve a two-site oxidative addition of phenol giving the iridaphenoxyphosphorane species IrHCl(PPh3)(L1OPh) (3'). In contrast, reactions of 1 with benzenethiol and benzeneselenol do not engage L1 and instead proceed via metal-centered oxidative addition of the chalcogen-hydrogen bond. These findings establish metal-ligand cooperation involving nonspectator reactivity of tricoordinate phosphorus ligands." @default.
- W4307431063 created "2022-11-01" @default.
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- W4307431063 date "2022-10-27" @default.
- W4307431063 modified "2023-09-24" @default.
- W4307431063 title "Two-Site O–H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand" @default.
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- W4307431063 doi "https://doi.org/10.1021/jacs.2c10087" @default.
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