FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4307454802> ?p ?o ?g. }

• W4307454802 endingPage "155466" @default.
• W4307454802 startingPage "155466" @default.
• W4307454802 abstract "Microwave guided the fusion of MOFs derivatives with Cu-O-Ce active surface by the non-thermal effect, and greatly reduced the synthesis temperature of the optimal CuO/CeO 2 catalyst for 100% CO conversion in H 2 stream. • Non-thermal microwave fuse facilitate the formation of evenly-distributed Cu-O-Ce interface. • Unique self-migration of metal species exists during microwave fuse of Cu-MOF and Ce-MOF mixture. • In-situ Raman and in-situ DRIFTs reveal the mechanism of synergistic redox enhancement by microwave. • Microwave pyrolysis fusion provides Cu2+-Ovac-Ce3+ to promote CO preferential oxidation. • The optimal activity derived temperature is reduced by 200 ℃ via microwave pyrolysis. Engineering of uniformly-distributed and well-combined multi-component interface is sustainable but challenging for acquiring heterogeneous catalysts. Herein, the low energy consumption of microwave-fuse preparation is imposed on metal-organic frameworks (MOFs) namely Cu-MOF and Ce-MOF to manipulate Cu-O-Ce interface for preferential CO oxidation in H 2 -rich stream. By comprehensive characterizations, it is discovered that a unique spontaneous-migration of active Cu species onto Ce matrix will be driven by the microwave-fuse to form evenly-distributed and compactly-integrated Cu-O-Ce interface at low temperature, which is 200 ℃ lower than that required by traditional pyrolysis, clearly indicating the unique non-thermal function of microwave processing on fine-tuning oxide composite interface. In-situ Raman and in-situ DRIFTs further elucidate the improvement on synergistic redox feature along Cu 2+ -O vac -Ce 3+ , leading to 100% conversion of CO at 75-170 ℃. These findings suggest that the unique self-migration of active metal species driven by non-thermal microwave-fuse is worthy of noting as an applicable strategy to acquire efficient multi-component solid interface for advanced heterogeneous catalysis as well as the current system for preferential CO oxidation in H 2 ." @default.
• W4307454802 created "2022-11-01" @default.
• W4307454802 creator A5027014551 @default.
• W4307454802 creator A5031383444 @default.
• W4307454802 creator A5039877318 @default.
• W4307454802 creator A5045327023 @default.
• W4307454802 creator A5045815499 @default.
• W4307454802 creator A5056248574 @default.
• W4307454802 creator A5056500391 @default.
• W4307454802 creator A5073216396 @default.
• W4307454802 date "2023-02-01" @default.
• W4307454802 modified "2023-10-17" @default.
• W4307454802 title "Microwave non-thermal fusion of MOFs derived Cu-O-Ce interface for boosting CO preferential oxidation" @default.
• W4307454802 cites W2008764522 @default.
• W4307454802 cites W2114217026 @default.
• W4307454802 cites W2282248941 @default.
• W4307454802 cites W2471355668 @default.
• W4307454802 cites W2612369154 @default.
• W4307454802 cites W2616799570 @default.
• W4307454802 cites W2629280134 @default.
• W4307454802 cites W2765927313 @default.
• W4307454802 cites W2766144101 @default.
• W4307454802 cites W2790695684 @default.
• W4307454802 cites W2790853952 @default.
• W4307454802 cites W2800456129 @default.
• W4307454802 cites W2804351053 @default.
• W4307454802 cites W2809313391 @default.
• W4307454802 cites W2857136719 @default.
• W4307454802 cites W2884454586 @default.
• W4307454802 cites W2894765051 @default.
• W4307454802 cites W2897578584 @default.
• W4307454802 cites W2900895018 @default.
• W4307454802 cites W2913137153 @default.
• W4307454802 cites W2914425145 @default.
• W4307454802 cites W2917488426 @default.
• W4307454802 cites W2956094601 @default.
• W4307454802 cites W2975002304 @default.
• W4307454802 cites W2976091655 @default.
• W4307454802 cites W2979385198 @default.
• W4307454802 cites W2990053947 @default.
• W4307454802 cites W3002099957 @default.
• W4307454802 cites W3006747298 @default.
• W4307454802 cites W3015505612 @default.
• W4307454802 cites W3025124795 @default.
• W4307454802 cites W3048540862 @default.
• W4307454802 cites W3083863137 @default.
• W4307454802 cites W3087403603 @default.
• W4307454802 cites W3096978285 @default.
• W4307454802 cites W3110952643 @default.
• W4307454802 cites W3126110053 @default.
• W4307454802 cites W3128533780 @default.
• W4307454802 cites W3132871199 @default.
• W4307454802 cites W3137750537 @default.
• W4307454802 cites W3144032478 @default.
• W4307454802 cites W3154568662 @default.
• W4307454802 cites W3159981694 @default.
• W4307454802 cites W3170806313 @default.
• W4307454802 cites W3176968731 @default.
• W4307454802 cites W3185585058 @default.
• W4307454802 cites W3195308269 @default.
• W4307454802 cites W3206419778 @default.
• W4307454802 cites W4224078602 @default.
• W4307454802 cites W4236639119 @default.
• W4307454802 doi "https://doi.org/10.1016/j.apsusc.2022.155466" @default.
• W4307454802 hasPublicationYear "2023" @default.
• W4307454802 type Work @default.
• W4307454802 citedByCount "2" @default.
• W4307454802 countsByYear W43074548022023 @default.
• W4307454802 crossrefType "journal-article" @default.
• W4307454802 hasAuthorship W4307454802A5027014551 @default.
• W4307454802 hasAuthorship W4307454802A5031383444 @default.
• W4307454802 hasAuthorship W4307454802A5039877318 @default.
• W4307454802 hasAuthorship W4307454802A5045327023 @default.
• W4307454802 hasAuthorship W4307454802A5045815499 @default.
• W4307454802 hasAuthorship W4307454802A5056248574 @default.
• W4307454802 hasAuthorship W4307454802A5056500391 @default.
• W4307454802 hasAuthorship W4307454802A5073216396 @default.
• W4307454802 hasConcept C119857082 @default.
• W4307454802 hasConcept C121332964 @default.
• W4307454802 hasConcept C127413603 @default.
• W4307454802 hasConcept C138885662 @default.
• W4307454802 hasConcept C158525013 @default.
• W4307454802 hasConcept C171250308 @default.
• W4307454802 hasConcept C185592680 @default.
• W4307454802 hasConcept C192562407 @default.
• W4307454802 hasConcept C204530211 @default.
• W4307454802 hasConcept C2779227376 @default.
• W4307454802 hasConcept C2779281663 @default.
• W4307454802 hasConcept C41008148 @default.
• W4307454802 hasConcept C41895202 @default.
• W4307454802 hasConcept C42360764 @default.
• W4307454802 hasConcept C44838205 @default.
• W4307454802 hasConcept C46686674 @default.
• W4307454802 hasConcept C76155785 @default.
• W4307454802 hasConcept C97355855 @default.
• W4307454802 hasConceptScore W4307454802C119857082 @default.
• W4307454802 hasConceptScore W4307454802C121332964 @default.
• W4307454802 hasConceptScore W4307454802C127413603 @default.

• next