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- W4307492810 endingPage "17039" @default.
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- W4307492810 abstract "We have synthesized chiral aza-boraspirobifluorenes and evaluated their structural and photophysical properties. Enantiomers were separated by chiral HPLC on a semi-preparative scale, and the absolute stereochemistry was determined by comparison of experimental circular dichroism (CD) spectra and theoretical electronic CD (ECD) spectra. A kinetic analysis combined with theoretical calculations revealed that the rate-determining step of the racemization involves the cleavage of the B-N bond." @default.
- W4307492810 created "2022-11-02" @default.
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- W4307492810 date "2022-01-01" @default.
- W4307492810 modified "2023-09-26" @default.
- W4307492810 title "Synthesis and stereochemistry of chiral aza-boraspirobifluorenes with tetrahedral boron-stereogenic centers" @default.
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- W4307492810 doi "https://doi.org/10.1039/d2dt03303h" @default.
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