Matches in SemOpenAlex for { <https://semopenalex.org/work/W4307553278> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W4307553278 endingPage "7252" @default.
- W4307553278 startingPage "7252" @default.
- W4307553278 abstract "In this work, we compared the hydride-donating ability of five-membered benzoheterocyclic compounds (FMB) and six-membered benzoheterocyclic compounds (SMB), isomers of DMBI and DMIZ and of DMPZ and DMPX, using detailed thermodynamic driving forces [ΔGo (XH)], kinetic intrinsic barriers (ΔG≠XH/X), and thermo-kinetic parameters [ΔG≠° (XH)]. For DMBI and DMIZ, the values of ΔGo (XH), ΔG≠XH/X, and ΔG≠° (XH) are 49.2 and 53.7 kcal/mol, 35.88 and 42.04 kcal/mol, and 42.54 and 47.87 kcal/mol, respectively. For DMPZ and DMPX, the values of ΔGo (XH), ΔG≠XH/X, and ΔG≠° (XH) are 73.2 and 79.5 kcal/mol, 35.34 and 25.02 kcal/mol, and 54.27 and 52.26 kcal/mol, respectively. It is easy to see that the FMB isomers are thermodynamically dominant and that the SMB isomers are kinetically dominant. Moreover, according to the analysis of ΔG≠° (XH), compared to the SMB isomers, the FMB isomers have a stronger hydride-donating ability in actual chemical reactions." @default.
- W4307553278 created "2022-11-03" @default.
- W4307553278 creator A5084030628 @default.
- W4307553278 creator A5090286314 @default.
- W4307553278 date "2022-10-25" @default.
- W4307553278 modified "2023-10-17" @default.
- W4307553278 title "Comparison of the Hydride-Donating Ability and Activity of Five- and Six-Membered Benzoheterocyclic Compounds in Acetonitrile" @default.
- W4307553278 cites W1761001352 @default.
- W4307553278 cites W1868808028 @default.
- W4307553278 cites W1963507005 @default.
- W4307553278 cites W1964655456 @default.
- W4307553278 cites W1972676767 @default.
- W4307553278 cites W1973336624 @default.
- W4307553278 cites W1973514430 @default.
- W4307553278 cites W1988442083 @default.
- W4307553278 cites W1990586537 @default.
- W4307553278 cites W1992738284 @default.
- W4307553278 cites W2001608982 @default.
- W4307553278 cites W2007322724 @default.
- W4307553278 cites W2015813013 @default.
- W4307553278 cites W2024661749 @default.
- W4307553278 cites W2037568638 @default.
- W4307553278 cites W2042413076 @default.
- W4307553278 cites W2056236132 @default.
- W4307553278 cites W2069136345 @default.
- W4307553278 cites W2072084159 @default.
- W4307553278 cites W2097546089 @default.
- W4307553278 cites W2105374479 @default.
- W4307553278 cites W2110507517 @default.
- W4307553278 cites W2118011560 @default.
- W4307553278 cites W2122843273 @default.
- W4307553278 cites W2132947775 @default.
- W4307553278 cites W2165005649 @default.
- W4307553278 cites W2290417402 @default.
- W4307553278 cites W2338288944 @default.
- W4307553278 cites W2483796603 @default.
- W4307553278 cites W2580402345 @default.
- W4307553278 cites W2808999647 @default.
- W4307553278 cites W2945385843 @default.
- W4307553278 cites W2951116386 @default.
- W4307553278 cites W3194604453 @default.
- W4307553278 cites W4225287022 @default.
- W4307553278 cites W4293221329 @default.
- W4307553278 doi "https://doi.org/10.3390/molecules27217252" @default.
- W4307553278 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36364079" @default.
- W4307553278 hasPublicationYear "2022" @default.
- W4307553278 type Work @default.
- W4307553278 citedByCount "1" @default.
- W4307553278 countsByYear W43075532782023 @default.
- W4307553278 crossrefType "journal-article" @default.
- W4307553278 hasAuthorship W4307553278A5084030628 @default.
- W4307553278 hasAuthorship W4307553278A5090286314 @default.
- W4307553278 hasBestOaLocation W43075532781 @default.
- W4307553278 hasConcept C121332964 @default.
- W4307553278 hasConcept C135889238 @default.
- W4307553278 hasConcept C147789679 @default.
- W4307553278 hasConcept C155647269 @default.
- W4307553278 hasConcept C178790620 @default.
- W4307553278 hasConcept C185592680 @default.
- W4307553278 hasConcept C2777463227 @default.
- W4307553278 hasConcept C2777961443 @default.
- W4307553278 hasConcept C512968161 @default.
- W4307553278 hasConcept C62520636 @default.
- W4307553278 hasConceptScore W4307553278C121332964 @default.
- W4307553278 hasConceptScore W4307553278C135889238 @default.
- W4307553278 hasConceptScore W4307553278C147789679 @default.
- W4307553278 hasConceptScore W4307553278C155647269 @default.
- W4307553278 hasConceptScore W4307553278C178790620 @default.
- W4307553278 hasConceptScore W4307553278C185592680 @default.
- W4307553278 hasConceptScore W4307553278C2777463227 @default.
- W4307553278 hasConceptScore W4307553278C2777961443 @default.
- W4307553278 hasConceptScore W4307553278C512968161 @default.
- W4307553278 hasConceptScore W4307553278C62520636 @default.
- W4307553278 hasIssue "21" @default.
- W4307553278 hasLocation W43075532781 @default.
- W4307553278 hasLocation W43075532782 @default.
- W4307553278 hasLocation W43075532783 @default.
- W4307553278 hasLocation W43075532784 @default.
- W4307553278 hasOpenAccess W4307553278 @default.
- W4307553278 hasPrimaryLocation W43075532781 @default.
- W4307553278 hasRelatedWork W1863538272 @default.
- W4307553278 hasRelatedWork W1985832542 @default.
- W4307553278 hasRelatedWork W1993529795 @default.
- W4307553278 hasRelatedWork W2004031742 @default.
- W4307553278 hasRelatedWork W2032892660 @default.
- W4307553278 hasRelatedWork W2091559720 @default.
- W4307553278 hasRelatedWork W2369886796 @default.
- W4307553278 hasRelatedWork W2808434441 @default.
- W4307553278 hasRelatedWork W4289132675 @default.
- W4307553278 hasRelatedWork W771627636 @default.
- W4307553278 hasVolume "27" @default.
- W4307553278 isParatext "false" @default.
- W4307553278 isRetracted "false" @default.
- W4307553278 workType "article" @default.