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- W4307645982 endingPage "110112" @default.
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- W4307645982 abstract "Using methods of static magnetic susceptibility, UV and visible spectrometry and conductometry, dimethylformamide solution of iron(II) complex with tris(pyrazol-1-yl)methane (HC(pz)3) having the composition [Fe(HC(pz)3)2]ns2 (ns = 2-naphthalene sulfonate) has been studied. In solution, as in the solid state, this compound exhibits a spin crossover of 1A1 ↔ 5T2, while in solution it is shifted to a region of lower temperatures and is sharper. It is shown that at a given concentration of 2.5 × 10−4 mol/L at 298 K, the molar electrical conductivity for the [Fe(HC(pz)3)2]ns2 complex in dimethylformamide is Λ298k = 100 ± 2 Ohm−1cm2 mol−1. Solutions of the [Fe(HC(pz)3)2]ns2 complex in a polar aprotic solvent with high dielectric permittivity are characterized by a high degree of dissociation by the type of 1,1-charging electrolyte. The dependences of the logarithm of the electrical conductivity of the studied solutions as a function of the logarithm of concentration and of 1/T are linear. The values of the electrolyte dissociation constant, pK = 2.3, and the activation energy of the charge transfer process, Ea = 5815 J/mol, are calculated. It is shown that a change in the spin state of the central atom of the complex in solution does not lead to changes in the nature of electrical conductivity and does not change Ea." @default.
- W4307645982 created "2022-11-04" @default.
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- W4307645982 date "2022-12-01" @default.
- W4307645982 modified "2023-10-05" @default.
- W4307645982 title "Investigation of solutions of iron(II) complexes with tris(pyrazol-1-yl)methane, possessing the spin-crossover phenomenon" @default.
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- W4307645982 doi "https://doi.org/10.1016/j.inoche.2022.110112" @default.
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