FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4307900545> ?p ?o ?g. }

• W4307900545 endingPage "368" @default.
• W4307900545 startingPage "359" @default.
• W4307900545 abstract "Nonoxidative dehydrogenation of ethane and nitrous oxide decomposition were coupled in a protonic ceramic fuel cell membrane reactor to achieve simultaneous generation of electricity, ethylene and decomposition of nitrous oxide. • Pr 0.6 Sr 0.4 Fe 0.8 Nb 0.1 Cu 0.1 O 3−δ was developed with high reduction tolerance and abundant oxygen vacancies. • Pr 0.6 Sr 0.4 Fe 0.8 Nb 0.1 Cu 0.1 O 3−δ exhibits excellent catalytic activity towards the NDE reaction for ethylene production. • Simultaneous generation of electricity, ethylene and decomposition of nitrous oxide were successfully achieved in a protonic ceramic fuel cell membrane reactor. • The maximum power density of the cell reaches 208 mW cm −2 at 750 °C, with high ethane conversion (45.2%), ethylene selectivity (92.5%), and nitrous oxide conversion (19.0%). Ethylene, one of the most widely produced building blocks in the petrochemical industry, has received intense attention. Ethylene production, using electrochemical hydrogen pump-facilitated nonoxidative dehydrogenation of ethane (NDE) to ethylene, is an emerging and promising route, promoting the transformation of the ethylene industry from energy-intensive steam cracking process to new electrochemical membrane reactor technology. In this work, the NDE reaction is incorporated into a BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3− δ electrolyte-supported protonic ceramic fuel cell membrane reactor to co-generate electricity and ethylene, utilizing the Nb and Cu doped perovskite oxide Pr 0.6 Sr 0.4 Fe 0.8 Nb 0.1 Cu 0.1 O 3− δ (PSFNCu) as anode catalytic layer. Due to the doping of Nb and Cu, PSFNCu was endowed with high reduction tolerance and rich oxygen vacancies, showing excellent NDE catalytic performance. The maximum power density of the assembled reactor reaches 200 mW cm −2 at 750 °C, with high ethane conversion (44.9%) and ethylene selectivity (92.7%). Moreover, the nitrous oxide decomposition was first coupled in the protonic ceramic fuel cell membrane reactor to consume the permeated protons. As a result, the generation of electricity, ethylene and decomposition of nitrous oxide can be simultaneously obtained by a single reactor. Specifically, the maximum power density of the cell reaches 208 mW cm −2 at 750 °C, with high ethane conversion (45.2%), ethylene selectivity (92.5%), and nitrous oxide conversion (19.0%). This multi-win technology is promising for not only the production of chemicals and energy but also greenhouse gas reduction." @default.
• W4307900545 created "2022-11-06" @default.
• W4307900545 creator A5002543242 @default.
• W4307900545 creator A5014539863 @default.
• W4307900545 creator A5041414390 @default.
• W4307900545 creator A5051254330 @default.
• W4307900545 creator A5077303230 @default.
• W4307900545 creator A5078776283 @default.
• W4307900545 date "2023-02-01" @default.
• W4307900545 modified "2023-10-17" @default.
• W4307900545 title "Simultaneous generation of electricity, ethylene and decomposition of nitrous oxide via protonic ceramic fuel cell membrane reactor" @default.
• W4307900545 cites W1996923858 @default.
• W4307900545 cites W1999621610 @default.
• W4307900545 cites W2012684293 @default.
• W4307900545 cites W2064625673 @default.
• W4307900545 cites W2084557106 @default.
• W4307900545 cites W2118356455 @default.
• W4307900545 cites W2128892456 @default.
• W4307900545 cites W2131416620 @default.
• W4307900545 cites W2157256895 @default.
• W4307900545 cites W2167590372 @default.
• W4307900545 cites W2218721340 @default.
• W4307900545 cites W2475545598 @default.
• W4307900545 cites W2480918537 @default.
• W4307900545 cites W2517710042 @default.
• W4307900545 cites W2615093193 @default.
• W4307900545 cites W2735122123 @default.
• W4307900545 cites W2750258290 @default.
• W4307900545 cites W2788721861 @default.
• W4307900545 cites W2794952270 @default.
• W4307900545 cites W2800358655 @default.
• W4307900545 cites W2887904016 @default.
• W4307900545 cites W2898120292 @default.
• W4307900545 cites W2903162634 @default.
• W4307900545 cites W2944673620 @default.
• W4307900545 cites W2955552130 @default.
• W4307900545 cites W2958599979 @default.
• W4307900545 cites W2969880316 @default.
• W4307900545 cites W3006709736 @default.
• W4307900545 cites W3015501277 @default.
• W4307900545 cites W3027193272 @default.
• W4307900545 cites W3048606922 @default.
• W4307900545 cites W3082391312 @default.
• W4307900545 cites W3082884648 @default.
• W4307900545 cites W3086389945 @default.
• W4307900545 cites W3091867124 @default.
• W4307900545 cites W3105582854 @default.
• W4307900545 cites W3105982350 @default.
• W4307900545 cites W3127722911 @default.
• W4307900545 cites W3130216317 @default.
• W4307900545 cites W3135048457 @default.
• W4307900545 cites W3136186952 @default.
• W4307900545 cites W3138938415 @default.
• W4307900545 cites W3153130540 @default.
• W4307900545 cites W3160550949 @default.
• W4307900545 cites W3162005006 @default.
• W4307900545 cites W3177667634 @default.
• W4307900545 cites W3195738770 @default.
• W4307900545 cites W3196171312 @default.
• W4307900545 cites W3206108851 @default.
• W4307900545 cites W3209517022 @default.
• W4307900545 cites W3215522982 @default.
• W4307900545 cites W4200493475 @default.
• W4307900545 cites W4210537418 @default.
• W4307900545 cites W4221067759 @default.
• W4307900545 cites W4223915101 @default.
• W4307900545 cites W4224274690 @default.
• W4307900545 cites W4233133233 @default.
• W4307900545 cites W4290879889 @default.
• W4307900545 cites W4292517137 @default.
• W4307900545 doi "https://doi.org/10.1016/j.jechem.2022.10.035" @default.
• W4307900545 hasPublicationYear "2023" @default.
• W4307900545 type Work @default.
• W4307900545 citedByCount "4" @default.
• W4307900545 countsByYear W43079005452023 @default.
• W4307900545 crossrefType "journal-article" @default.
• W4307900545 hasAuthorship W4307900545A5002543242 @default.
• W4307900545 hasAuthorship W4307900545A5014539863 @default.
• W4307900545 hasAuthorship W4307900545A5041414390 @default.
• W4307900545 hasAuthorship W4307900545A5051254330 @default.
• W4307900545 hasAuthorship W4307900545A5077303230 @default.
• W4307900545 hasAuthorship W4307900545A5078776283 @default.
• W4307900545 hasConcept C119599485 @default.
• W4307900545 hasConcept C124681953 @default.
• W4307900545 hasConcept C127413603 @default.
• W4307900545 hasConcept C134132462 @default.
• W4307900545 hasConcept C15920480 @default.
• W4307900545 hasConcept C159985019 @default.
• W4307900545 hasConcept C161790260 @default.
• W4307900545 hasConcept C178790620 @default.
• W4307900545 hasConcept C185592680 @default.
• W4307900545 hasConcept C191897082 @default.
• W4307900545 hasConcept C192562407 @default.
• W4307900545 hasConcept C206658404 @default.
• W4307900545 hasConcept C2777573673 @default.
• W4307900545 hasConcept C2777801237 @default.
• W4307900545 hasConcept C2778551180 @default.
• W4307900545 hasConcept C2778597550 @default.

• next