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• W4307922491 abstract "Following the work of Giulio Racah and others from the 1940s onward, the rotational symmetry of atoms and ions, e.g., the conservation of angular momentum, has been utilized in order to efficiently predict atomic behavior, from their level structure to the interaction with external fields, and up to the angular distribution and polarization of either emitted or scattered photons and electrons, while this rotational symmetry becomes apparent first of all in the block-diagonal structure of the Hamiltonian matrix, it also suggests a straight and consequent use of symmetry-adapted interaction amplitudes in expressing the observables of most atomic properties and processes. We here emphasize and discuss how atomic structure theory benefits from exploiting this symmetry, especially if open-shell atoms and ions in different charge states need to be combined with electrons in the continuum. By making use of symmetry-adapted amplitudes, a large number of excitation, ionization, recombination or even cascade processes can be formulated rather independently of the atomic shell structure and in a language close to the formal theory. The consequent use of these amplitudes in existing codes such as Grasp will therefore qualify them to deal with the recently emerging demands for developing general-purpose tools for atomic computations." @default.
• W4307922491 created "2022-11-06" @default.
• W4307922491 creator A5047063187 @default.
• W4307922491 date "2022-11-01" @default.
• W4307922491 modified "2023-10-14" @default.
• W4307922491 title "Application of Symmetry-Adapted Atomic Amplitudes" @default.
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• W4307922491 doi "https://doi.org/10.3390/atoms10040127" @default.
• W4307922491 hasPublicationYear "2022" @default.
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