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• W4307965866 endingPage "15311" @default.
• W4307965866 startingPage "15301" @default.
• W4307965866 abstract "A novel protocol for the construction of highly functionalized indolizine derivatives, that is, 1H-pyrrolo[3,4-b]indolizine-1,3-diones (PIZDOs, 3) from 2-(pyridine-2-yl)acetates and maleimides via a regioselective oxidative [3 + 2] annulation was developed. The cascade oxidative reaction was enabled by heating a mixture of the two substrates in the presence of Ag2CO3 as an oxidant and Cu(OAc)·H2O as a catalyst in chlorobenzene. Consequently, a series of PIZDOs 3 were synthesized with high regioselectivity in moderate yields. This protocol can be used in the synthesis of functionalized PIZDOs via the one-pot oxidative annulation reaction rather than through multistep reactions, which is suitable for both combinatorial and parallel syntheses of PIZDOs." @default.
• W4307965866 created "2022-11-06" @default.
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• W4307965866 date "2022-11-02" @default.
• W4307965866 modified "2023-09-29" @default.
• W4307965866 title "Cu-Catalyzed Oxidative [3 + 2] Annulation of 2-(Pyridine-2-yl)acetates with Maleimides: Synthesis of 1<i>H</i>-Pyrrolo[3,4-<i>b</i>]indolizine-1,3-diones" @default.
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• W4307965866 doi "https://doi.org/10.1021/acs.joc.2c01879" @default.
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