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• W4307971159 abstract "Iminolactones are an important class of heterocyclic compounds. Thus, the development of an efficient strategy for their preparation becomes highly desirable. A new method for the transformation of carboxamides into iminolactones via copper-catalyzed intramolecular C(sp3)-H bond functionalization is reported herein. A series of primary, secondary and tertiary C(sp3)-H bonds were all accommodated to afford iminolactones through a cascade process which involves amidyl radical intermediate generation, 1,5-HAT (hydrogen atom transfer), and ensuing cyclization." @default.
• W4307971159 created "2022-11-06" @default.
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• W4307971159 date "2022-01-01" @default.
• W4307971159 modified "2023-09-28" @default.
• W4307971159 title "Copper-catalyzed intramolecular iminolactonization cyclization reactions of remote C(sp³)–H bonds in carboxamides" @default.
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• W4307971159 doi "https://doi.org/10.1039/d2ob01711c" @default.
• W4307971159 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36321617" @default.
• W4307971159 hasPublicationYear "2022" @default.
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