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- W4308045289 abstract "A highly efficient and mild method for [3 + 2] cycloaddition of β-sulfonyl-α,β-unsaturated ketones with terminal allenoates was well-explored and developed. The reactions were successfully performed by applying multifunctional chiral phosphine P6 which was screened from eight chiral phosphorus reagents to finally result in a variety of enantioenriched sulfone-substituted cyclopentenes with two chiral centers (up to 81% yield with 94% ee). Moreover, 2.5 mol% catalytic equivalents were proved to be feasible when this reaction was performed on a 10 mmol scale." @default.
- W4308045289 created "2022-11-07" @default.
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- W4308045289 date "2023-02-01" @default.
- W4308045289 modified "2023-10-14" @default.
- W4308045289 title "Enantioselective [3 + 2] cycloadditions of terminal allenoates with β-sulfonyl-α,β-unsaturated ketones" @default.
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- W4308045289 doi "https://doi.org/10.1016/j.gresc.2022.10.015" @default.
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