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- W4308068977 abstract "Glycerol is an important starting material for the production of value-added chemicals such as electronic materials and pharmaceuticals. We herein present a selective allylation reaction using allyl alcohol which is given from glycerol. First, we show the rhenium catalyzed high-yielding synthesis of allyl alcohol from glycerol through deoxydehydration reaction. Next, the selective N-allyl aniline synthesis from allyl alcohol with aniline is performed. The well-dispersed tungsten oxide supported on zirconium oxide can catalyze the reaction to produce the corresponding mono-allyl compound over 97% selectivity using a flow reactor. The developed catalyst is applicable to the production of various N-monoallyl anilines without the formation of N,N-diallyl anilines." @default.
- W4308068977 created "2022-11-08" @default.
- W4308068977 creator A5066414781 @default.
- W4308068977 date "2022-09-29" @default.
- W4308068977 modified "2023-10-18" @default.
- W4308068977 title "Selective monoallylation of anilines to form fine chemicals using allyl alcohol derived from glycerol" @default.
- W4308068977 doi "https://doi.org/10.21748/mjrr3569" @default.
- W4308068977 hasPublicationYear "2022" @default.
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