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- W4308077224 abstract "Molybdenum carbide has been demonstrated as a promising alternative to noble metal catalysts toward green and efficient hydrogen conversion. However, the suboptimal hydrogen adsorption free energy (∆ G H* ) and complex carbon reduction procedures remain crucial challenges. Herein, a gas-phase reaction approach based on the in-situ decomposition of hemicellulose and cellulose from natural wood was proposed for the design of highly active Mo 2 C nanoparticles that are tightly rooted into the hierarchical N-doped carbonized wood (denoted as Mo 2 C/N-CW). As expected, the Mo 2 C/N-CW catalyst exhibited low hydrogen evolution reaction (HER) overpotential (98 mV at 50 mA cm −2 ) and outstanding long-term durability. The theoretical findings show that the conjunction between Mo 2 C and N-CW can modulate the ∆ G H* to the desired level, thereby improving the HER activity. The proposed approach enabled by the decompositions from natural biomass to construct high-performance electrocatalysts opens a novel perspective for the efficient production of hydrogen energy. • A novel strategy enabled by the in-situ decomposition of hydrocarbons from natural wood is proposed. • Highly-active Mo 2 C nanoparticles tightly rooted into hierarchical N-CW are configured. • Conjunction between Mo 2 C and N-CW can modulate the ∆ G H* to a desired level." @default.
- W4308077224 created "2022-11-08" @default.
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- W4308077224 date "2023-02-01" @default.
- W4308077224 modified "2023-10-11" @default.
- W4308077224 title "In-situ decomposition of hydrocarbons from wood cell wall enables configuration of highly active and hierarchical catalyst for hydrogen evolution reaction" @default.
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- W4308077224 doi "https://doi.org/10.1016/j.jallcom.2022.167898" @default.
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