Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308118968> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W4308118968 endingPage "7428" @default.
- W4308118968 startingPage "7428" @default.
- W4308118968 abstract "The oxidative electrochemistry of cymantrene, CpMn(CO)3 (1; Cp = [η5-C5H5]-), was examined in ionic liquids (ILs) composed of anions of varying Lewis base properties. It was observed that the cyclic voltammetric responses strongly depended on the nucleophilic properties of the IL anion. Still, all observations are consistent with the initial formation of 1+ followed by an attack from the IL anion. In bis(trifluoromethylsulfonyl)amide [NTf2]-based ILs, the process shows close to ideal electrochemical reversibility as the reaction between 1+ and [NTf2] anion is very slow. On the other hand, in tetrafluoroborate and trifluoromethanesulfonate-based IL, the oxidation of 1 shows different levels of electrochemical reversibility with a marked sign of anion attack to 1+. In contrast, 1 exhibits an irreversible oxidation process in hexafluorophosphate-based IL. The reaction rate constants for the interaction of 1+ with the different IL anions were estimated by fitting the experimental data to digital simulations of the proposed mechanism. Besides, the use of [NTf2]-based ILs as a supporting electrolyte in CH2Cl2 was also examined. The oxidation process of 1 shows a close to ideal electrochemical reversibility but low to non-chemical reversibility. This study illustrates the wide range of electrochemical environments available with ILs and demonstrates their limited utility for investigating the redox properties of metal carbonyl compounds. It also intends to warn the reader on how the IL media may influence an electrochemical study if care is not exercised." @default.
- W4308118968 created "2022-11-08" @default.
- W4308118968 creator A5073598360 @default.
- W4308118968 date "2022-11-01" @default.
- W4308118968 modified "2023-09-30" @default.
- W4308118968 title "Ionic Liquids Effect on the Stability of 17-Electron Cation Product of the Electrochemical Oxidation of Cymantrene" @default.
- W4308118968 cites W1964776246 @default.
- W4308118968 cites W1967352625 @default.
- W4308118968 cites W1971467527 @default.
- W4308118968 cites W1989234866 @default.
- W4308118968 cites W1990664188 @default.
- W4308118968 cites W1994765455 @default.
- W4308118968 cites W1995338475 @default.
- W4308118968 cites W1998426520 @default.
- W4308118968 cites W2011396592 @default.
- W4308118968 cites W2029808537 @default.
- W4308118968 cites W2040338073 @default.
- W4308118968 cites W2048356455 @default.
- W4308118968 cites W2053260739 @default.
- W4308118968 cites W2054270313 @default.
- W4308118968 cites W2060373299 @default.
- W4308118968 cites W2060757838 @default.
- W4308118968 cites W2068811257 @default.
- W4308118968 cites W2074314343 @default.
- W4308118968 cites W2085202403 @default.
- W4308118968 cites W2086123691 @default.
- W4308118968 cites W2089550466 @default.
- W4308118968 cites W2093839473 @default.
- W4308118968 cites W2095093579 @default.
- W4308118968 cites W2110267483 @default.
- W4308118968 cites W2146582209 @default.
- W4308118968 cites W2157698358 @default.
- W4308118968 cites W2175912931 @default.
- W4308118968 cites W2949476817 @default.
- W4308118968 cites W2950318149 @default.
- W4308118968 cites W2952423535 @default.
- W4308118968 cites W3028912049 @default.
- W4308118968 cites W4236340890 @default.
- W4308118968 cites W4241598867 @default.
- W4308118968 cites W4245595995 @default.
- W4308118968 cites W2010896842 @default.
- W4308118968 doi "https://doi.org/10.3390/molecules27217428" @default.
- W4308118968 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36364253" @default.
- W4308118968 hasPublicationYear "2022" @default.
- W4308118968 type Work @default.
- W4308118968 citedByCount "0" @default.
- W4308118968 crossrefType "journal-article" @default.
- W4308118968 hasAuthorship W4308118968A5073598360 @default.
- W4308118968 hasBestOaLocation W43081189681 @default.
- W4308118968 hasConcept C147789679 @default.
- W4308118968 hasConcept C154881586 @default.
- W4308118968 hasConcept C161790260 @default.
- W4308118968 hasConcept C17525397 @default.
- W4308118968 hasConcept C178790620 @default.
- W4308118968 hasConcept C178907741 @default.
- W4308118968 hasConcept C179104552 @default.
- W4308118968 hasConcept C185592680 @default.
- W4308118968 hasConcept C2777598222 @default.
- W4308118968 hasConcept C2780707935 @default.
- W4308118968 hasConcept C2780872544 @default.
- W4308118968 hasConcept C52859227 @default.
- W4308118968 hasConcept C55904794 @default.
- W4308118968 hasConcept C65024703 @default.
- W4308118968 hasConceptScore W4308118968C147789679 @default.
- W4308118968 hasConceptScore W4308118968C154881586 @default.
- W4308118968 hasConceptScore W4308118968C161790260 @default.
- W4308118968 hasConceptScore W4308118968C17525397 @default.
- W4308118968 hasConceptScore W4308118968C178790620 @default.
- W4308118968 hasConceptScore W4308118968C178907741 @default.
- W4308118968 hasConceptScore W4308118968C179104552 @default.
- W4308118968 hasConceptScore W4308118968C185592680 @default.
- W4308118968 hasConceptScore W4308118968C2777598222 @default.
- W4308118968 hasConceptScore W4308118968C2780707935 @default.
- W4308118968 hasConceptScore W4308118968C2780872544 @default.
- W4308118968 hasConceptScore W4308118968C52859227 @default.
- W4308118968 hasConceptScore W4308118968C55904794 @default.
- W4308118968 hasConceptScore W4308118968C65024703 @default.
- W4308118968 hasIssue "21" @default.
- W4308118968 hasLocation W43081189681 @default.
- W4308118968 hasLocation W43081189682 @default.
- W4308118968 hasLocation W43081189683 @default.
- W4308118968 hasLocation W43081189684 @default.
- W4308118968 hasOpenAccess W4308118968 @default.
- W4308118968 hasPrimaryLocation W43081189681 @default.
- W4308118968 hasRelatedWork W1978962015 @default.
- W4308118968 hasRelatedWork W2005546069 @default.
- W4308118968 hasRelatedWork W2050443402 @default.
- W4308118968 hasRelatedWork W2050473805 @default.
- W4308118968 hasRelatedWork W2067184332 @default.
- W4308118968 hasRelatedWork W2079696792 @default.
- W4308118968 hasRelatedWork W2080689260 @default.
- W4308118968 hasRelatedWork W2085422999 @default.
- W4308118968 hasRelatedWork W2098188577 @default.
- W4308118968 hasRelatedWork W2191248974 @default.
- W4308118968 hasVolume "27" @default.
- W4308118968 isParatext "false" @default.
- W4308118968 isRetracted "false" @default.
- W4308118968 workType "article" @default.