Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308156714> ?p ?o ?g. }
- W4308156714 endingPage "110178" @default.
- W4308156714 startingPage "110178" @default.
- W4308156714 abstract "Development of efficient and economical non-precious metal catalysts for dehydrogenation of ammonia borane is an important way to store and release hydrogen. Vacancy-engineered defective catalysts with modulated electronic structure allow ideal adsorption and dissociation of reactant molecules for the optimized catalytic activity. In this study, we report a facile synthesis of cobalt-defective Co3O4 (VCo-Co3O4) nanocatalyst by the calcination of layered cobalt glycerate as a key precursor. The stacked cobalt-oxygen sheets and interlayer bound glycerate anions in a layered structure are favorable for introducing cation vacancy during calcination process. The obtained Vco-Co3O4 exhibits outstanding catalytic activity for the hydrolysis of ammonia borane, along with a high hydrogen production rate of 934 mL min−1 gCat-1 and a low activation energy of 32.65 kJ mol−1. The catalytic performance of the VCo-Co3O4 catalyst can be well maintained for consecutive five cycles. The current study establishes a new example of cation vacancy strategy to facilitate the hydrolysis of ammonia borane for hydrogen generation." @default.
- W4308156714 created "2022-11-08" @default.
- W4308156714 creator A5019592083 @default.
- W4308156714 creator A5027804591 @default.
- W4308156714 creator A5051781523 @default.
- W4308156714 creator A5056650380 @default.
- W4308156714 creator A5060100701 @default.
- W4308156714 creator A5067358601 @default.
- W4308156714 date "2022-12-01" @default.
- W4308156714 modified "2023-09-28" @default.
- W4308156714 title "Co-vacancy rich Co3O4 catalyst enables efficient hydrogen generation from the hydrolysis of ammonia borane" @default.
- W4308156714 cites W2009794593 @default.
- W4308156714 cites W2015248375 @default.
- W4308156714 cites W2036795793 @default.
- W4308156714 cites W2065542858 @default.
- W4308156714 cites W2088011491 @default.
- W4308156714 cites W2514502080 @default.
- W4308156714 cites W2558317446 @default.
- W4308156714 cites W2562950171 @default.
- W4308156714 cites W2565767854 @default.
- W4308156714 cites W2579678688 @default.
- W4308156714 cites W2587773561 @default.
- W4308156714 cites W2595355981 @default.
- W4308156714 cites W2789342549 @default.
- W4308156714 cites W2793201711 @default.
- W4308156714 cites W2794662762 @default.
- W4308156714 cites W2807794086 @default.
- W4308156714 cites W2890826540 @default.
- W4308156714 cites W2899232133 @default.
- W4308156714 cites W2929651773 @default.
- W4308156714 cites W2933131738 @default.
- W4308156714 cites W2965774557 @default.
- W4308156714 cites W2965969901 @default.
- W4308156714 cites W2968252870 @default.
- W4308156714 cites W2972406448 @default.
- W4308156714 cites W3006454728 @default.
- W4308156714 cites W3008317649 @default.
- W4308156714 cites W3012223754 @default.
- W4308156714 cites W3027253540 @default.
- W4308156714 cites W3032808863 @default.
- W4308156714 cites W3089304433 @default.
- W4308156714 cites W3100423154 @default.
- W4308156714 cites W3118565330 @default.
- W4308156714 cites W3122163525 @default.
- W4308156714 cites W3123119493 @default.
- W4308156714 cites W3136434397 @default.
- W4308156714 cites W3214623917 @default.
- W4308156714 cites W4205151846 @default.
- W4308156714 cites W4206438376 @default.
- W4308156714 cites W4214839043 @default.
- W4308156714 cites W4214904625 @default.
- W4308156714 cites W4224266290 @default.
- W4308156714 cites W4224285868 @default.
- W4308156714 cites W4224293214 @default.
- W4308156714 cites W4226380202 @default.
- W4308156714 cites W4242647086 @default.
- W4308156714 cites W4286255955 @default.
- W4308156714 cites W4289024938 @default.
- W4308156714 doi "https://doi.org/10.1016/j.inoche.2022.110178" @default.
- W4308156714 hasPublicationYear "2022" @default.
- W4308156714 type Work @default.
- W4308156714 citedByCount "3" @default.
- W4308156714 countsByYear W43081567142023 @default.
- W4308156714 crossrefType "journal-article" @default.
- W4308156714 hasAuthorship W4308156714A5019592083 @default.
- W4308156714 hasAuthorship W4308156714A5027804591 @default.
- W4308156714 hasAuthorship W4308156714A5051781523 @default.
- W4308156714 hasAuthorship W4308156714A5056650380 @default.
- W4308156714 hasAuthorship W4308156714A5060100701 @default.
- W4308156714 hasAuthorship W4308156714A5067358601 @default.
- W4308156714 hasConcept C102931765 @default.
- W4308156714 hasConcept C114221277 @default.
- W4308156714 hasConcept C119889771 @default.
- W4308156714 hasConcept C147789679 @default.
- W4308156714 hasConcept C161790260 @default.
- W4308156714 hasConcept C178790620 @default.
- W4308156714 hasConcept C179104552 @default.
- W4308156714 hasConcept C181258405 @default.
- W4308156714 hasConcept C185592680 @default.
- W4308156714 hasConcept C202189072 @default.
- W4308156714 hasConcept C2776382133 @default.
- W4308156714 hasConcept C2778470625 @default.
- W4308156714 hasConcept C512968161 @default.
- W4308156714 hasConcept C515602321 @default.
- W4308156714 hasConcept C7082614 @default.
- W4308156714 hasConcept C8010536 @default.
- W4308156714 hasConcept C94412978 @default.
- W4308156714 hasConceptScore W4308156714C102931765 @default.
- W4308156714 hasConceptScore W4308156714C114221277 @default.
- W4308156714 hasConceptScore W4308156714C119889771 @default.
- W4308156714 hasConceptScore W4308156714C147789679 @default.
- W4308156714 hasConceptScore W4308156714C161790260 @default.
- W4308156714 hasConceptScore W4308156714C178790620 @default.
- W4308156714 hasConceptScore W4308156714C179104552 @default.
- W4308156714 hasConceptScore W4308156714C181258405 @default.
- W4308156714 hasConceptScore W4308156714C185592680 @default.
- W4308156714 hasConceptScore W4308156714C202189072 @default.
- W4308156714 hasConceptScore W4308156714C2776382133 @default.