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• W4308156774 abstract "Silicon, as the highest capacity lithium-ion battery (LIB) anode material, has been commercialized due to its mature industrial foundation, abundant reserves, and environmental benign. However, its relatively slow Li-ionic and electronic conductivity impede its large-scale application when fast charging and discharging are required. To significantly improve the reaction kinetics, we propose to co-introduce aluminum and phosphorus into silicon at the same time, forming a novel family AlSixP (x = 1, 3, 6) solid solutions. As anodes for LIBs, the equimolar compound of AlSiP presents longer cycling stability and much higher rate performance than Si counterparts due to the faster electronic and Li-ionic conductivity and the rich underlithiated electrochemical intermediates of which reduce the volume variation. The AlSi3P and AlSi6P are also prepared and present similar Li-storage superiority, suggesting the AlSixP series materials are promising to be utilized in the real world." @default.
• W4308156774 created "2022-11-08" @default.
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• W4308156774 date "2023-01-01" @default.
• W4308156774 modified "2023-10-18" @default.
• W4308156774 title "AlSixP: A new family of ternary Si-based anodes for Li-ion batteries with superior Li-storage properties" @default.
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• W4308156774 doi "https://doi.org/10.1016/j.ceramint.2022.10.311" @default.
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