FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308183277> ?p ?o ?g. }

• W4308183277 endingPage "1302" @default.
• W4308183277 startingPage "1294" @default.
• W4308183277 abstract "Fabricating microscale helical structures from small molecules remains challenging due to the disfavoured torsion energy of twisted architectures and elusory chirality control at different hierarchical levels of assemblies. Here we report a combined solution-interface-directed assembly strategy for the formation of hierarchically self-assembled helical microtoroids with micrometre-scale lengths. A drop-evaporation assembly protocol on a solid substrate from pre-assembled intermediate colloids of enantiomeric binaphthalene bisurea compounds leads to microtoroids with preferred helicity, which depends on the molecular chirality of the starting enantiomers. Collective variable-temperature spectroscopic analyses, electron microscopy characterizations and theoretical simulations reveal a mechanism that simultaneously induces aggregation and cyclization to impart a favourable handedness to the final microtoroidal structures. We then use monodispersed luminescent helical toroids as chiral light-harvesting antenna and show excellent Förster resonance energy transfer ability to a co-hosted chiral acceptor dye, leading to unique circularly polarized luminescence. Our results shed light on the potential of the combined solution-interface-directed self-assembly approach in directing hierarchical chirality control and may advance the prospect of chiral superstructures at a higher length scale." @default.
• W4308183277 created "2022-11-09" @default.
• W4308183277 creator A5058453644 @default.
• W4308183277 creator A5077931134 @default.
• W4308183277 creator A5081626495 @default.
• W4308183277 creator A5081780353 @default.
• W4308183277 creator A5083418140 @default.
• W4308183277 date "2022-11-03" @default.
• W4308183277 modified "2023-10-17" @default.
• W4308183277 title "Hierarchically self-assembled homochiral helical microtoroids" @default.
• W4308183277 cites W1865890606 @default.
• W4308183277 cites W1968480115 @default.
• W4308183277 cites W1978067626 @default.
• W4308183277 cites W1994486848 @default.
• W4308183277 cites W2002742052 @default.
• W4308183277 cites W2006532602 @default.
• W4308183277 cites W2009068495 @default.
• W4308183277 cites W2012710474 @default.
• W4308183277 cites W2017627877 @default.
• W4308183277 cites W2024269331 @default.
• W4308183277 cites W2024388338 @default.
• W4308183277 cites W2056305440 @default.
• W4308183277 cites W2059880325 @default.
• W4308183277 cites W2063456885 @default.
• W4308183277 cites W2067901272 @default.
• W4308183277 cites W2071746729 @default.
• W4308183277 cites W2076025950 @default.
• W4308183277 cites W2086227779 @default.
• W4308183277 cites W2087831519 @default.
• W4308183277 cites W2150852355 @default.
• W4308183277 cites W2172591732 @default.
• W4308183277 cites W2299015718 @default.
• W4308183277 cites W2329551239 @default.
• W4308183277 cites W2534278659 @default.
• W4308183277 cites W2606223814 @default.
• W4308183277 cites W2611058893 @default.
• W4308183277 cites W2738346868 @default.
• W4308183277 cites W2755024593 @default.
• W4308183277 cites W2755630419 @default.
• W4308183277 cites W2773471129 @default.
• W4308183277 cites W2916046566 @default.
• W4308183277 cites W2919645010 @default.
• W4308183277 cites W2922700839 @default.
• W4308183277 cites W2945589311 @default.
• W4308183277 cites W2960787887 @default.
• W4308183277 cites W2971534020 @default.
• W4308183277 cites W2977027632 @default.
• W4308183277 cites W2980453861 @default.
• W4308183277 cites W3007488362 @default.
• W4308183277 cites W3042577164 @default.
• W4308183277 cites W3042952686 @default.
• W4308183277 cites W3099296370 @default.
• W4308183277 cites W3177405163 @default.
• W4308183277 cites W3202625860 @default.
• W4308183277 cites W3216131608 @default.
• W4308183277 cites W4223911005 @default.
• W4308183277 cites W4230321861 @default.
• W4308183277 cites W4251979646 @default.
• W4308183277 doi "https://doi.org/10.1038/s41565-022-01234-w" @default.
• W4308183277 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36329269" @default.
• W4308183277 hasPublicationYear "2022" @default.
• W4308183277 type Work @default.
• W4308183277 citedByCount "23" @default.
• W4308183277 countsByYear W43081832772022 @default.
• W4308183277 countsByYear W43081832772023 @default.
• W4308183277 crossrefType "journal-article" @default.
• W4308183277 hasAuthorship W4308183277A5058453644 @default.
• W4308183277 hasAuthorship W4308183277A5077931134 @default.
• W4308183277 hasAuthorship W4308183277A5081626495 @default.
• W4308183277 hasAuthorship W4308183277A5081780353 @default.
• W4308183277 hasAuthorship W4308183277A5083418140 @default.
• W4308183277 hasBestOaLocation W43081832771 @default.
• W4308183277 hasConcept C121332964 @default.
• W4308183277 hasConcept C124668440 @default.
• W4308183277 hasConcept C148869448 @default.
• W4308183277 hasConcept C159467904 @default.
• W4308183277 hasConcept C171250308 @default.
• W4308183277 hasConcept C185592680 @default.
• W4308183277 hasConcept C192468462 @default.
• W4308183277 hasConcept C192562407 @default.
• W4308183277 hasConcept C204795200 @default.
• W4308183277 hasConcept C20621625 @default.
• W4308183277 hasConcept C26856880 @default.
• W4308183277 hasConcept C49040817 @default.
• W4308183277 hasConcept C52703039 @default.
• W4308183277 hasConcept C62520636 @default.
• W4308183277 hasConcept C75473681 @default.
• W4308183277 hasConceptScore W4308183277C121332964 @default.
• W4308183277 hasConceptScore W4308183277C124668440 @default.
• W4308183277 hasConceptScore W4308183277C148869448 @default.
• W4308183277 hasConceptScore W4308183277C159467904 @default.
• W4308183277 hasConceptScore W4308183277C171250308 @default.
• W4308183277 hasConceptScore W4308183277C185592680 @default.
• W4308183277 hasConceptScore W4308183277C192468462 @default.
• W4308183277 hasConceptScore W4308183277C192562407 @default.
• W4308183277 hasConceptScore W4308183277C204795200 @default.
• W4308183277 hasConceptScore W4308183277C20621625 @default.
• W4308183277 hasConceptScore W4308183277C26856880 @default.

• next