Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308183543> ?p ?o ?g. }
- W4308183543 endingPage "27808" @default.
- W4308183543 startingPage "27793" @default.
- W4308183543 abstract "Thiosemicarbazone-linked 3-acetylpyridine (T3AP), was synthesized and tested on copper strips in hydrochloric acid. Gravimetric measurements and electrochemical impedance spectroscopy were used to investigate the optimized inhibitory behavior of T3AP using the response surface methodology (RSM), with the optimized result obtained using a temperature of 42.90 °C, acid concentration of 2.38 M, inhibitor concentration of 3.80 mM, and time of 18.97 h, with inhibition efficiency up to approximately 93%. Validation of the experimental and predicted RSM showed that no significant difference in the inhibition efficiency with the confidence level value up to 97% was obtained. The isotherm study shows that T3AP obeys the Langmuir isotherm adsorption model, with physisorption and chemisorption adsorption mechanisms. The effectiveness of inhibitor performance of T3AP can be visually observed using scanning electron microscopy and X-ray photoelectron spectroscopy. The characterization revealed that the reactive S and N atoms in the T3AP inhibitor form strong chemical adsorption through N-Cu and Cu-S bonds on the copper surface. Computational analysis was also carried out, and we found that the stable energy gap between the occupied and unoccupied molecular orbitals (4.6891 eV) and high binding energy (540.962 kJ mol-1) adsorption from molecular dynamics were in agreement with the experimental findings." @default.
- W4308183543 created "2022-11-09" @default.
- W4308183543 creator A5000195384 @default.
- W4308183543 creator A5010106614 @default.
- W4308183543 creator A5013417166 @default.
- W4308183543 creator A5053736184 @default.
- W4308183543 creator A5058568196 @default.
- W4308183543 date "2022-01-01" @default.
- W4308183543 modified "2023-09-25" @default.
- W4308183543 title "Gravimetric and electrochemical statistical optimizations for improving copper corrosion resistance in hydrochloric acid using thiosemicarbazone-linked 3-acetylpyridine" @default.
- W4308183543 cites W1999828948 @default.
- W4308183543 cites W2013473960 @default.
- W4308183543 cites W2018461754 @default.
- W4308183543 cites W2021902704 @default.
- W4308183543 cites W2041145816 @default.
- W4308183543 cites W2052318753 @default.
- W4308183543 cites W2065283695 @default.
- W4308183543 cites W2066117078 @default.
- W4308183543 cites W2088376206 @default.
- W4308183543 cites W2125085520 @default.
- W4308183543 cites W2171614809 @default.
- W4308183543 cites W2247910776 @default.
- W4308183543 cites W2265379025 @default.
- W4308183543 cites W2314861923 @default.
- W4308183543 cites W2760270739 @default.
- W4308183543 cites W2766938126 @default.
- W4308183543 cites W2767678741 @default.
- W4308183543 cites W2796778237 @default.
- W4308183543 cites W2799959381 @default.
- W4308183543 cites W2805752666 @default.
- W4308183543 cites W2887286372 @default.
- W4308183543 cites W2891499157 @default.
- W4308183543 cites W2913587980 @default.
- W4308183543 cites W2944805615 @default.
- W4308183543 cites W2952927565 @default.
- W4308183543 cites W2953255085 @default.
- W4308183543 cites W2968413527 @default.
- W4308183543 cites W2979966570 @default.
- W4308183543 cites W2990584397 @default.
- W4308183543 cites W3004227146 @default.
- W4308183543 cites W3007667827 @default.
- W4308183543 cites W3016050895 @default.
- W4308183543 cites W3021875719 @default.
- W4308183543 cites W3035577863 @default.
- W4308183543 cites W3043826631 @default.
- W4308183543 cites W3082024243 @default.
- W4308183543 cites W3087204329 @default.
- W4308183543 cites W3091456269 @default.
- W4308183543 cites W3092123422 @default.
- W4308183543 cites W3092306471 @default.
- W4308183543 cites W3122372055 @default.
- W4308183543 cites W3129052015 @default.
- W4308183543 cites W3184751406 @default.
- W4308183543 cites W3201245012 @default.
- W4308183543 doi "https://doi.org/10.1039/d2ra05192c" @default.
- W4308183543 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36320253" @default.
- W4308183543 hasPublicationYear "2022" @default.
- W4308183543 type Work @default.
- W4308183543 citedByCount "2" @default.
- W4308183543 countsByYear W43081835432023 @default.
- W4308183543 crossrefType "journal-article" @default.
- W4308183543 hasAuthorship W4308183543A5000195384 @default.
- W4308183543 hasAuthorship W4308183543A5010106614 @default.
- W4308183543 hasAuthorship W4308183543A5013417166 @default.
- W4308183543 hasAuthorship W4308183543A5053736184 @default.
- W4308183543 hasAuthorship W4308183543A5058568196 @default.
- W4308183543 hasBestOaLocation W43081835431 @default.
- W4308183543 hasConcept C113196181 @default.
- W4308183543 hasConcept C12143843 @default.
- W4308183543 hasConcept C127413603 @default.
- W4308183543 hasConcept C13965031 @default.
- W4308183543 hasConcept C147789679 @default.
- W4308183543 hasConcept C150394285 @default.
- W4308183543 hasConcept C17525397 @default.
- W4308183543 hasConcept C175708663 @default.
- W4308183543 hasConcept C178790620 @default.
- W4308183543 hasConcept C179104552 @default.
- W4308183543 hasConcept C185592680 @default.
- W4308183543 hasConcept C2777436746 @default.
- W4308183543 hasConcept C2780050857 @default.
- W4308183543 hasConcept C33790079 @default.
- W4308183543 hasConcept C42360764 @default.
- W4308183543 hasConcept C52859227 @default.
- W4308183543 hasConcept C544778455 @default.
- W4308183543 hasConcept C7040849 @default.
- W4308183543 hasConcept C83591994 @default.
- W4308183543 hasConcept C96278889 @default.
- W4308183543 hasConceptScore W4308183543C113196181 @default.
- W4308183543 hasConceptScore W4308183543C12143843 @default.
- W4308183543 hasConceptScore W4308183543C127413603 @default.
- W4308183543 hasConceptScore W4308183543C13965031 @default.
- W4308183543 hasConceptScore W4308183543C147789679 @default.
- W4308183543 hasConceptScore W4308183543C150394285 @default.
- W4308183543 hasConceptScore W4308183543C17525397 @default.
- W4308183543 hasConceptScore W4308183543C175708663 @default.
- W4308183543 hasConceptScore W4308183543C178790620 @default.
- W4308183543 hasConceptScore W4308183543C179104552 @default.
- W4308183543 hasConceptScore W4308183543C185592680 @default.