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- W4308183721 abstract "A ferrocene surfactant can be switched between single and double head form (FcN+ C12 /Fc+ N+ C12 ) triggered by redox reaction. FcN+ C12 can neither stabilize an O/W emulsion alone nor an oil-in-dispersion emulsion in combination with alumina nanoparticles due to the steric hindrance of the ferrocene group. However, such steric hindrance can be overcome by increasing the charge density in Fc+ N+ C12 , so that oil-in-dispersion emulsions can be co-stabilized by Fc+ N+ C12 and alumina nanoparticles at very low concentrations (1×10-7 M (≈50 ppb) and 0.001 wt %, respectively). Not only can reversible formation/destabilization of oil-in-dispersion emulsions be achieved by redox reaction, but also reversible transformation between oil-in-dispersion emulsions and Pickering emulsions can be obtained through reversing the charge of alumina particles by adjusting the pH. The results provide a new protocol for the design of surfactants for stabilization of smart oil-in-dispersion emulsions." @default.
- W4308183721 created "2022-11-09" @default.
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- W4308183721 date "2022-12-19" @default.
- W4308183721 modified "2023-10-07" @default.
- W4308183721 title "Charge Density Overcomes Steric Hindrance of Ferrocene Surfactant in Switchable Oil‐in‐Dispersion Emulsions" @default.
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- W4308183721 doi "https://doi.org/10.1002/anie.202210050" @default.
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