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Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308189659> ?p ?o ?g. }

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• W4308189659 startingPage "8423" @default.
• W4308189659 abstract "Herein, a novel [Rh]2-catalyzed three-component reaction of readily accessible indoles, diazo compounds, and allylic compounds is developed via a relay carbene-induced C-H functionalization and allylic alkylation process, affording diverse C3-substituted indoles bearing all-carbon quaternary centers in good yields with high atom and step economy. Moreover, good enantioselective control is achieved using a (-)-DIOP type ligand, thus providing an efficient method for constructing enantioenriched indole derivatives bearing an all-carbon quaternary stereocenter." @default.
• W4308189659 created "2022-11-09" @default.
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• W4308189659 date "2022-11-04" @default.
• W4308189659 modified "2023-10-14" @default.
• W4308189659 title "Selective Construction of All-Carbon Quaternary Centers via Relay Catalysis of Indole C–H Functionalization/Allylic Alkylation" @default.
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• W4308189659 doi "https://doi.org/10.1021/acs.orglett.2c03543" @default.
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