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- W4308271726 abstract "Abstract On-surface synthesis is at the verge of emerging as the method of choice for the generation and visualization of unstable or unconventional molecules, which could not be obtained via traditional synthetic methods. A case in point is the on-surface synthesis of the structurally elusive cyclotriphosphazene (P 3 N 3 ), an inorganic aromatic analogue of benzene. Here, we report the preparation of this fleetingly existing species on a Cu(111) surface at 5.2 K through molecular manipulation with unprecedented precision, i.e., voltage pulse-induced sextuple dechlorination of an ultra-small (about 6 Å) hexachlorophosphazene P 3 N 3 Cl 6 molecule by the tip of a scanning probe microscope. Real-space atomic-level imaging of cyclotriphosphazene reveals its planar D 3h -symmetric ring structure. Furthermore, this synthetic strategy has been expanded to generate cyclotriphosphazene via photolysis of a hexaazide precursor P 3 N 21 for complementary measurements by matrix isolation infrared and ultraviolet spectroscopy." @default.
- W4308271726 created "2022-11-10" @default.
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- W4308271726 date "2022-11-04" @default.
- W4308271726 modified "2023-10-18" @default.
- W4308271726 title "On-Surface Synthesis and Real-Space Visualization of Aromatic P3N3" @default.
- W4308271726 doi "https://doi.org/10.21203/rs.3.rs-2169632/v1" @default.
- W4308271726 hasPublicationYear "2022" @default.
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