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• W4308347102 startingPage "116952" @default.
• W4308347102 abstract "Lithium titanate (Li4Ti5O12) anode materials are widely popular because of their exceptional structural properties that could offer extremely long life and high current rate with safe operation. In-depth research works have been going on to mitigate the limiting factors like poor conduction and diffusion of lithium titanate for the electrode applications in the lithium-ion battery. Elemental doping and surface coating were found to be promising methods to overcome these challenges and enhance the capacity for widespread application. Herein, ex-situ carbon-coated tin (Sn4+) doped lithium titanate was synthesized via conventional solid-state synthesis. Its electrochemical performances were analyzed and compared with its pristine phase by making half cells with lithium. The results were highly promising as the Li4Sn0.05Ti4.95O12 with 5 wt% carbon coating exhibited significantly reduced cell impedance (Rct = 49.48 Ω), enhanced electrode lithium-ion diffusion coefficient (D = 2.40×10−11 cm2 s−1), and superior specific capacity (Q = 173.1 mAh/g at 0.1 C) over pristine lithium titanate (Rct = 274.2 Ω, D = 2.71×10−12 cm2 s−1, and Q = 145 mAh/g). The cell could also run for 1000 cycles with minimum capacity fade (82 % retention) at a 1 C rate." @default.
• W4308347102 created "2022-11-11" @default.
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• W4308347102 date "2022-12-01" @default.
• W4308347102 modified "2023-10-15" @default.
• W4308347102 title "Electrochemical characterizations of carbon decorated tin doped lithium titanate for lithium-ion battery anode applications" @default.
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• W4308347102 doi "https://doi.org/10.1016/j.jelechem.2022.116952" @default.
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