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- W4308348831 abstract "In this work, we show that non-superabsorbent, thermo-responsive poly(N-isopropyl acrylamide) (PNIPAM) hydrogel particles (< 250 μm) can reduce autogenous shrinkage in cement paste and improve early-age stiffening that can be caused by traditional superabsorbent polymers (SAPs). Swelling measurements in DI water and cement filtrate solution suggest that SAP-induced early-age stiffening is caused by its super-absorbency in low-ionic solutions – a behavior not exhibited by non-superabsorbent PNIPAM. PNIPAM exhibited a 29% and 60% reduction in autogenous shrinkage strain at 14 days when used alone (0.3 wt.% PNIPAM) and in combination with SAP (0.15% PNIPAM, 0.15% SAP), respectively, compared to a Control with no polymer addition. Furthermore, an addition of 0.3 wt.% PNIPAM exhibited a ∼29% and ∼37% decrease in static yield stress compared to a Control and 0.3 wt.% SAP-modified cement pastes, respectively. Taken together, the results provide initial evidence to suggest that the use of hydrogels as internal curing agents may not necessarily require super-absorbency to reduce autogenous shrinkage. Non-superabsorbent hydrogels, like PNIPAM, may help reduce autogenous shrinkage while alleviating the effects of SAP-induced early-age stiffening." @default.
- W4308348831 created "2022-11-11" @default.
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- W4308348831 date "2022-12-01" @default.
- W4308348831 modified "2023-10-02" @default.
- W4308348831 title "Thermo-responsive poly(N-isopropylacrylamide) (PNIPAM) hydrogel particles improve workability loss and autogenous shrinkage in cement paste" @default.
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- W4308348831 doi "https://doi.org/10.1016/j.cement.2022.100049" @default.
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