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- W4308350247 abstract "Comprehensive Summary A rhodium‐catalyzed denitrogenative carbonylation of 1,2,3‐thiadiazole with alkynes to construct (benzo)thiochromenones is developed. Both terminal and internal alkynes were compatible in this [3+2+1] cycloaddition, affording a broad range of poly‐substituted thiochromenones. Unsymmetrical alkyne substrates exhibited good regioselectivity. It is noteworthy that the present strategy could be used to construct both monocyclic and benzo‐thiochromenones, and it is a novel example of denitrogenative transannulation with CO insertion." @default.
- W4308350247 created "2022-11-11" @default.
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- W4308350247 date "2023-01-10" @default.
- W4308350247 modified "2023-10-16" @default.
- W4308350247 title "<scp>Rhodium‐Catalyzed</scp> Transannulation of 1,2, <scp>3‐Thiazoles</scp> with Alkynes for the Direct Synthesis of Thiochromenones" @default.
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- W4308350247 doi "https://doi.org/10.1002/cjoc.202200603" @default.
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