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- W4308368009 abstract "We report herein the in situ generation of difluoromethoxylated ketenimines. This novel intermediate is readily obtained from the corresponding oxime through a Beckmann rearrangement. The reactivity potential of this species is demonstrated as it easily undergoes addition of various nucleophiles, with a great modularity of the starting oxime. The broad applicability of this transformation leads to a chemical library of original molecules bearing −OCHF2, an Emergent Fluorinated Group (EFG)." @default.
- W4308368009 created "2022-11-11" @default.
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- W4308368009 date "2022-11-07" @default.
- W4308368009 modified "2023-10-03" @default.
- W4308368009 title "Ketenimines as Intermediates To Access Difluoromethoxylated Scaffolds" @default.
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- W4308368009 doi "https://doi.org/10.1021/acs.orglett.2c03283" @default.
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