Matches in SemOpenAlex for { <https://semopenalex.org/work/W4308369675> ?p ?o ?g. }
- W4308369675 abstract "Common nonlinear optical (NLO) crystals consist of traditional functional building blocks with inherent optical limitation. Herein, inspired by traditional (B3 O6 )3- inorganic building block, we theoretically identified a new type of organic functional building blocks and then successfully synthesized the first cyamelurate NLO crystal, Ba(H2 C6 N7 O3 )2 ⋅ 8 H2 O. To our surprise, the constituent (H2 C6 N7 O3 )- building block is not in structurally optimal arrangement, but Ba(H2 C6 N7 O3 )2 ⋅ 8 H2 O exhibits excellent optical properties including wide band gap of 4.10 eV, very large birefringence of 0.24@550 nm, and exceptionally strong second-harmonic generation (SHG) response of about 12×KH2 PO4 . Both the SHG response and birefringence are much larger than those of commercial NLO crystal β-BaB2 O4 with optimally aligned (B3 O6 )3- building block. Theoretical calculations suggest that the expanded π-conjugation delocalization within (H2 C6 N7 O3 )- vs (B3 O6 )3- should be responsible to the enhanced performance. This work implies that there is still much room to develop new NLO crystals with excellent functional building blocks that may be longly neglected." @default.
- W4308369675 created "2022-11-11" @default.
- W4308369675 creator A5009288153 @default.
- W4308369675 creator A5019423466 @default.
- W4308369675 creator A5022442919 @default.
- W4308369675 creator A5023243771 @default.
- W4308369675 creator A5048614698 @default.
- W4308369675 creator A5048674582 @default.
- W4308369675 creator A5050572506 @default.
- W4308369675 creator A5069930364 @default.
- W4308369675 creator A5072469527 @default.
- W4308369675 creator A5090610046 @default.
- W4308369675 date "2022-12-13" @default.
- W4308369675 modified "2023-10-17" @default.
- W4308369675 title "A High‐Performance Nonlinear Optical Crystal with a Building Block Containing Expanded π‐Delocalization" @default.
- W4308369675 cites W1927854349 @default.
- W4308369675 cites W1972392650 @default.
- W4308369675 cites W1998614691 @default.
- W4308369675 cites W2010492482 @default.
- W4308369675 cites W2019951471 @default.
- W4308369675 cites W2020226532 @default.
- W4308369675 cites W2038516125 @default.
- W4308369675 cites W2041893040 @default.
- W4308369675 cites W2052512097 @default.
- W4308369675 cites W2060342473 @default.
- W4308369675 cites W2089255009 @default.
- W4308369675 cites W2107141326 @default.
- W4308369675 cites W2143061652 @default.
- W4308369675 cites W2149913710 @default.
- W4308369675 cites W2161854807 @default.
- W4308369675 cites W2165788110 @default.
- W4308369675 cites W2329073581 @default.
- W4308369675 cites W2330525299 @default.
- W4308369675 cites W2385556747 @default.
- W4308369675 cites W2587681799 @default.
- W4308369675 cites W2592339122 @default.
- W4308369675 cites W2884066176 @default.
- W4308369675 cites W2913044713 @default.
- W4308369675 cites W2944751964 @default.
- W4308369675 cites W2972329729 @default.
- W4308369675 cites W2983767342 @default.
- W4308369675 cites W3007239955 @default.
- W4308369675 cites W3086496578 @default.
- W4308369675 cites W3111165386 @default.
- W4308369675 cites W3117907337 @default.
- W4308369675 cites W3120695990 @default.
- W4308369675 cites W3134398315 @default.
- W4308369675 cites W3156525688 @default.
- W4308369675 cites W3164242020 @default.
- W4308369675 cites W3165310905 @default.
- W4308369675 cites W3168465525 @default.
- W4308369675 cites W3201566841 @default.
- W4308369675 cites W3201680705 @default.
- W4308369675 cites W4200261527 @default.
- W4308369675 cites W4200459039 @default.
- W4308369675 cites W4205467399 @default.
- W4308369675 cites W4210796610 @default.
- W4308369675 cites W4210870964 @default.
- W4308369675 cites W4213146001 @default.
- W4308369675 cites W4233901914 @default.
- W4308369675 cites W4241494193 @default.
- W4308369675 cites W4245688462 @default.
- W4308369675 cites W4248964525 @default.
- W4308369675 doi "https://doi.org/10.1002/anie.202215145" @default.
- W4308369675 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36341522" @default.
- W4308369675 hasPublicationYear "2022" @default.
- W4308369675 type Work @default.
- W4308369675 citedByCount "9" @default.
- W4308369675 countsByYear W43083696752023 @default.
- W4308369675 crossrefType "journal-article" @default.
- W4308369675 hasAuthorship W4308369675A5009288153 @default.
- W4308369675 hasAuthorship W4308369675A5019423466 @default.
- W4308369675 hasAuthorship W4308369675A5022442919 @default.
- W4308369675 hasAuthorship W4308369675A5023243771 @default.
- W4308369675 hasAuthorship W4308369675A5048614698 @default.
- W4308369675 hasAuthorship W4308369675A5048674582 @default.
- W4308369675 hasAuthorship W4308369675A5050572506 @default.
- W4308369675 hasAuthorship W4308369675A5069930364 @default.
- W4308369675 hasAuthorship W4308369675A5072469527 @default.
- W4308369675 hasAuthorship W4308369675A5090610046 @default.
- W4308369675 hasConcept C120665830 @default.
- W4308369675 hasConcept C121332964 @default.
- W4308369675 hasConcept C125743686 @default.
- W4308369675 hasConcept C158622935 @default.
- W4308369675 hasConcept C178790620 @default.
- W4308369675 hasConcept C185592680 @default.
- W4308369675 hasConcept C192562407 @default.
- W4308369675 hasConcept C199360897 @default.
- W4308369675 hasConcept C2524010 @default.
- W4308369675 hasConcept C2777210771 @default.
- W4308369675 hasConcept C2781285689 @default.
- W4308369675 hasConcept C2991936344 @default.
- W4308369675 hasConcept C30713254 @default.
- W4308369675 hasConcept C33923547 @default.
- W4308369675 hasConcept C41008148 @default.
- W4308369675 hasConcept C49040817 @default.
- W4308369675 hasConcept C520434653 @default.
- W4308369675 hasConcept C62520636 @default.
- W4308369675 hasConcept C70050531 @default.
- W4308369675 hasConceptScore W4308369675C120665830 @default.