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- W4308371389 abstract "Hydroacylation of alkynes is undoubtedly the simplest and most atom-efficient approach for the synthesis of enones with diverse synthetic applications. Despite significant progress in hydroacylations, no hydroacylations exist that make use of aldehydes without a chelating group, especially when combined with terminal alkynes. Here we report a synergistic nickel–photocatalytic system that allows for the highly regio- and stereoselective hydroacylation of unactivated aldehydes and alkynes in milder conditions without the use of chelating groups." @default.
- W4308371389 created "2022-11-11" @default.
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- W4308371389 date "2022-11-07" @default.
- W4308371389 modified "2023-10-01" @default.
- W4308371389 title "Photoredox–Ni Dual Catalysis: Chelation-Free Hydroacylation of Terminal Alkynes" @default.
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- W4308371389 doi "https://doi.org/10.1021/acs.orglett.2c03481" @default.
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