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- W4308385773 abstract "Development of method with micro-volume reagent usage and high selectivity for rapid determination of valuable disease-related biomarkers is of great importance for disease surveillance. Herein, a novel ratiometric fluorescence capillary imprinted sensor was developed for highly selective fluorescence determination of sialic acid (SA) based on luminescent metal-organic framework (UiO-66-NH 2 ). In this strategy, the imprinted pre-polymer with double emissions was sucked into the capillary to grow imprinted layer on the inner wall of the capillary. In presence of SA, the blue fluorescence (440 nm) served as fluorescence response signal was quenched due to the electron transfer mechanism between metal organic framework and SA while the red fluorescence (655 nm) served as the reference signal was remained. Within SA concentration linear range of 1.0 × 10 −7 –3.0 × 10 −4 M, the ratiometric fluorescence capillary imprinted sensor was applied to detect SA in human serum and saliva samples successfully with a detection limit of 2.5 × 10 −8 M. A sensitive and selective fluorescence method with micro-volume sample consumption (15 μl) for determination of SA in practical samples was established. • A uniformly imprinted ratiometric fluorescence capillary sensor based on UiO-66-NH 2 was prepared. • The imprinted fluorescence capillary sensor achieved rapid and sensitive determination of SA. • The fluorescence capillary imprinted sensor showed micro-volume sample analysis (15 μl) for SA. • The imprinted fluorescence capillary sensor provided a new analysis method for rapid determination of SA with micro-volume reagent." @default.
- W4308385773 created "2022-11-11" @default.
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- W4308385773 date "2023-02-01" @default.
- W4308385773 modified "2023-10-03" @default.
- W4308385773 title "Imprinted ratiometric fluorescence capillary sensor based on UiO-66-NH2 for rapid determination of sialic acid" @default.
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- W4308385773 doi "https://doi.org/10.1016/j.talanta.2022.124081" @default.
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