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- W4308388546 abstract "Nanoparticles of Li0.35Zn0.30Co0.05Fe2.3O4 with average crystallite sizes of ∼7.3 nm and 69.6 nm are prepared by sol-gel method. Size of nanocrystallite in each case plays an important role in the thermal variation of magnetization. For small size, each nanocrystallite may be considered as single domain ordered core surrounded by a surface shell of disordered spins, which are fluctuating randomly. Also, there is a large deviation of Bloch’s law in case of magnetization vs temperature curves where exponent is larger compared to that of larger nanocrystallites. A steep increase in the magnetization is evidenced at lower temperatures, which is more prominent in case of nanocrystallites of smaller sizes. This additional magnetization comes from the surface spin contribution and is effective at T ≤ 100 K. Thus various novel features of magnetism are being evolved once the particle/nanocrystallite size is quite low." @default.
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- W4308388546 date "2022-12-01" @default.
- W4308388546 modified "2023-09-30" @default.
- W4308388546 title "Core-shell spin model of magnetization in Li-Zn-Co ferrite" @default.
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- W4308388546 doi "https://doi.org/10.1016/j.jmmm.2022.170157" @default.
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