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- W4308393623 abstract "Nitrenes and nitrenoids are highly reactive species and the proposed key intermediates in nitrogen-containing heterocyclic compound synthesis. In this work, we developed a practical method for the synthesis of phenanthridines by the reaction of oximes and Grignard reagents (with or without diethylzinc) via ring-expansion of magnesium coordinated nitrenoid complex as the key step. The method has been used to synthesize optically active planar chiral ferrocenyl phenanthridines." @default.
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- W4308393623 date "2022-11-29" @default.
- W4308393623 modified "2023-10-17" @default.
- W4308393623 title "Nitrenoid from Oxime: A Practical Synthesis of Planar Chiral Ferrocenyl Phenanthridines via Nitrene‐Involved Ring‐Expansion Reaction" @default.
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- W4308393623 doi "https://doi.org/10.1002/anie.202215530" @default.
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