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• W4308451968 endingPage "121278" @default.
• W4308451968 startingPage "121278" @default.
• W4308451968 abstract "The reactions of the (triflato)(meso-tetra(para-methoxyphenyl)porphyrinato)manganese(III) ([MnIII(TMPP)(SO3CF3)] complex with an excess of 4-dimethylaminopyridine (DMAP) and hexamethylenetetramine (HMTA) have been examined. These reactions yield crystalline [MnIII(TMPP)(DMAP)2](0.1Cl)(0.9SO3CF3)•2CHCl3 (I) and [MnIII(TMPP)(HMTA)2](SO3CF3)•2CH2Cl2 (II) complexes, respectively. The hyper d-type electronic spectra of I-II are characteristic for high-spin (S = 2) Mn(III) metalloporphyrins with very redshifted Soret bands. A cyclic voltammetry investigation was carried out on these two Mn(III) coordination compounds. The crystal structures of the solid complexes I-II were determined by X-ray single-crystal diffraction and elucidated by Hirshfeld surface approach. Furthermore, bioactivity of the H2TMPP free base, the [MnIII(TMPP)(SO3CF3)] starting material and complexes I-II, was assessed by a set of in vitro tests checking for antioxidant, antibacterial and antifungal (against several strains) effects." @default.
• W4308451968 created "2022-11-12" @default.
• W4308451968 creator A5002266720 @default.
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• W4308451968 date "2023-01-01" @default.
• W4308451968 modified "2023-10-17" @default.
• W4308451968 title "DMAP and HMTA manganese(III) meso-tetraphenylporphyrin-based coordination complexes: Syntheses, physicochemical properties, structural and biological activities" @default.
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