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- W4308452487 abstract "C - Si Bond cleavage is one of the key elemental steps for a wide variety of silicon-based transformations. However, the cleavage of unstrained Si-C(sp3) bonds catalyzed by transition metal are still in their infancy. They generally involve the insertion of a M - C(sp2) species into the C - Si bond and consequent intramolecular C(sp2)‒Si coupling to exclusively produce siloles. Here we report the Pd-catalyzed sila-spirocyclization, in which the Si-C(sp3) bond is activated by the insertion of a M - C(sp3) species and followed by the formation of a new C(sp3)‒Si bond, allowing the construction of diverse spirosilacycles. This reactivity mode, which is strongly supported by DFT calculations may open an avenue for the Si-C(sp3) bond cleavage and silacycle synthesis." @default.
- W4308452487 created "2022-11-12" @default.
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- W4308452487 date "2022-11-05" @default.
- W4308452487 modified "2023-10-05" @default.
- W4308452487 title "Sila-spirocyclization involving unstrained C(sp3)−Si bond cleavage" @default.
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- W4308452487 doi "https://doi.org/10.1038/s41467-022-34466-4" @default.
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